Tumgik
#page 5536
ao3feed-rickorty · 1 year
Text
A Secret Chord
by krsive
Morty Smith is about to learn who his Soulmate is. Rick Sanchez already knows that everything is going to change forever.
This is what Rick gets for fucking around with time travel when he was young and stupid.
Excerpt:
Pouting openly, Morty marched over to the door. He was ready to take a page from his grandfather’s book and tell whoever it was to piss off, but when he wrenched the door open he nearly fainted dead away. There, on his very own stoop, was Rick Sanchez. That would have been easy enough to accept–after all, Morty had seen the Citadel, and once Guard Ricks had even come to the house to interrogate his Rick about some fraud he had run (and, in the end, gotten away with). This was a completely different story, though. This Rick was young; younger than Morty’s parents, even.
Words: 5536, Chapters: 1/6, Language: English
Fandoms: Rick and Morty
Rating: Explicit
Warnings: Underage
Categories: M/M
Characters: Rick Sanchez, Flesh Curtains Rick, Morty Smith, The Smith family
Relationships: Rick Sanchez/Morty Smith
Additional Tags: Incest, Consensual Underage Sex, Soulmates, Time Travel, Jealous Rick Sanchez (Rick and Morty), Young Rick Sanchez (Rick and Morty), Two Ricks for the Price of One, Mutual Pining, Angst, Love Triangle, but also kind of not
Check it out on AO3 | https://archiveofourown.org/works/43829628
0 notes
formlab · 3 years
Photo
Tumblr media
Olivetti Summa 19 Calculator by Ettore Sotsass
https://www.moma.org/collection/works/105983?artist_id=5536&page=1&sov_referrer=artist
74 notes · View notes
Photo
Tumblr media
Destiel Trope Collection 2019 Day 9: Coffee Shop AU
rain is falling, looks like love | @alullabytoleaveby Rating: General Word Count: 5536 Main Tags and Warnings: coffee shop au, student!cas, barista!cas Summary: “Um. I didn’t order this.” Cas shrugs.“It’s on the house. Consider it a thank you for your patience.” Dean snorts. “Thanks, I guess. Although I’ve never been much of a muffin man. Honestly, I’d prefer a piece of pie,” he says with a winning smile. Cas determinedly doesn’t fall for it. “Beggars can’t be choosers, Dean. Eat your muffin.” -- OR: Cas works at a coffeeshop, Dean is a customer, and they're both ridiculously in love with each other.
...And One Awkward Barista To Go | @isolemnlyswear-iamsuperwholocked Rating: Teen & Up Word Count: 2113 Main Tags and Warnings: Alternate Universe, Alternate Universe - Modern Setting, Alternate Universe - Coffee Shops & Cafés, Alternate Universe - After College/University, Coffee Shop Employee Castiel, Post-High School, High School Crush, Tumblr Prompt, Based on a Tumblr Post Summary: Dean finally got out of his hometown to go to college, but when he comes back on break he passes the cafe where he first met his old crush, Castiel, and old memories make him go inside...because what are the chances he'll even still be there, anyway?
Noveltea & Coffee | @rustling-pages Rating: Explicit Word Count: 50064 Main Tags and Warnings: Magical Realism AU, Slow Burn, Mutual Pining Summary: Dean once thought his literary themed coffee shop ‘Noveltea & Coffee’ would be a better, more satisfying source of income than working as a mechanic. He thought people would come for the good coffee and stay for an even better book selection. He also thought he’d be running it with Sam, but that didn’t happen. Now he’s stuck with a bad mood he’s emoting all over the place, a lovingly created coffee shop no one ever frequents and a soul full of worry for the brother he no longer talks to. When Castiel – a defeated librarian turned accountant – comes stumbling in during a November downpour, things change so drastically for the better, it might as well be magic…
Not So Alone Anymore | @pherryt Rating: General Word Count: 4211 Main Tags and Warnings: a/b/o dynamics, omega!cas, omega!dean, alpha!michael, web designer!dean, Mpreg, abandoned!dean, Misunderstandings, Pining, Confessions, Cas owns a coffee shop, Angst and Fluff, Pups, past michael/dean Summary: Suddenly alone and pregnant, Dean’s resigned himself to raising his unborn pups by himself after Michael skips out on him for greener pastures. Along comes Cas. They get off on the wrong foot but maybe Dean isn’t so alone anymore...
Nobody's Fault But Mine | @peanutbutterjelly-pie Rating: General Word Count: 6139 Main Tags and Warnings: Alternate Universe, Fluff, Bakery, Misunderstandings, Mistaken Identity Summary: Castiel just should have listened. He seriously should have. But instead he found himself hypnotized by those beautiful green eyes and he totally missed the most important thing in the process.
50 Last Dates | @reaperlove77 Rating: Teen & Up Word Count: 1379 Main Tags and Warnings: pining Dean, clueless Cas, Humor, fluff, coffee shop au Summary: It was Dean's guilty pleasure, watching scruffy guy dump his various boyfriends, a real life soap opera. He really, really wanted to get to know blue eyes better, but come on, Dean doesn't date shady. But there's more to the story than he expected.
Autumn in His Eyes | @DesiraeLovesDestiel Rating: Explicit Word Count: 50464 Main Tags and Warnings: Bar Owner Dean/Artist Cas, Humor, Fluff, Angst with a happy ending, Smut, pining, minor character death, Summary: Castiel worked his ass off to escape his family and make a name for himself in the art world and now C.J. Krushnic was one of the most sought-after artists around. After years of abuse from his dysfunctional family, he was finally living as he pleased and answered to no one other than himself. Until his older brother, Lucifer, was arrested and found guilty of multiple homicides. Now the name C.J. Krushnic was synonymous with sex, lies, and murder. Castiel, exhausted and stressed by the constant paparazzi and speculation into his own psyche, goes into hiding, moving into an inherited property of his beloved grandmother’s in the cozy little town of Bear Claw, Vermont-where he meets one Dean Winchester. Dean, though not without his own baggage, is a kind and generous soul who unlocks something in Castiel. Seemingly not put off by his surliness-in fact, Dean seems to enjoy it- the kind bar owner reawakens Castiel’s muse, making him want to open up about his past and who he is. But Dean is too bright to deserve all of Castiel’s dark and the artist is determined not to let them become anything more than good friends. But Castiel soon learns that Dean has other plans.
Bean's | @lemonsorbae Rating: Teen & Up Word Count: 6787 Main Tags and Warnings: Alternate Universe, Alternate Universe - Coffee Shops & Cafés, Fluff Summary: When Dean had returned home from his third tour in Iraq, he’d begged the universe for a mundane life. No more guns, no more Arabic, no more shitty showers and MREs; Dean just wanted quiet.
Cakepocalypse! | @mittensmorgul Rating: Mature Word Count: 64145 Main Tags and Warnings: Alternate Universe - Canon Divergence, Post-Episode: s13e23 Let the Good Times Roll, Baker Dean Winchester, TV producer Castiel, Alternate Universe - Reality Show, 13.23 coda fic and therefore canon, Friends to Lovers, Love Confessions, Angst and Fluff and Smut, but mostly fluff with a dash of crack.. Summary: “What the hell you tryin’ to sell me?” Dean asked, folding his arms across his chest. “Not selling, Deano. Buying. Or at least, renting for the duration of a limited season run,” Gabriel said, as Dean’s frown deepened. “Have you ever dreamed of being a Hollywood superstar?” Dean laughed outright at that and shook his head, turning around to pick up his coffee again. “Man, no way in hell. You got the wrong guy.” Spoiler alert: He did not have the wrong guy.
The Angel Cake Challenge | @almaasi Rating: General Word Count: 8132 Main Tags and Warnings: Canon Universe, Fluff, Romance, Team Free Will 2.0, Day At The Beach, Mistaken For A Couple, Bakery and Coffee Shop, Food as a Metaphor for Love, Public Displays of Affection, Pet Names, Endearments, First Kiss, Closeted Dean Winchester, Coming Out, Openly Bisexual Dean Winchester, Crossovers & Fandom Fusions, Good Omens Summary: There's a kooky gay couple sitting in this little beachside bistro, at the table next to Dean. Dean's biggest mistake was telling them they looked cute together. Now they've noticed Cas, and they're silently encouraging Dean to be as openly affectionate as them. Dean didn't sign up for this challenge. But now? Hell, he's in it to win it.
Purple Horse in a Coffee Shop | @almaasi Rating: General Word Count: 8437 Main Tags and Warnings: Fluff, Crack, Alternate Universe - Human, Alternate Universe - Office, Pride Parades, Coffee Shops, Horses, Colorblindness, Pride, Workplace Relationship, Agender Castiel, Asexual Castiel, Wizard Castiel, Bisexual Dean, Prince Dean, Pansexual Sam Summary: Nobody expects to see a purple horse at a Pride parade. So, naturally, Dean Winchester is surprised to meet his office co-worker and long-term crush, Castiel, riding atop a magnificent steed - and dressed in full wizard regalia, no less. Somehow, Cas thinks he (and his decked-out horse) are wearing grey. They visit a coffee shop with their friends and family, trying to get to the bottom of this mix-up - and apparently the purple horse is coming too. “One medium black coffee with two sugars; one macchiato; three small soy lattes; one large decaf with a caramel shot - and ten apples, please.”
225 notes · View notes
lindasims2 · 5 years
Photo
Tumblr media Tumblr media Tumblr media Tumblr media Tumblr media Tumblr media Tumblr media Tumblr media Tumblr media
No AdFly Категория: отдельный низ Особенность: без талии и бедер Пол/Возраст: женский/взрослый, студенты, пожилой Swatches: 24 Credit: ts4 to ts2 and recolor by LindaSim shoe ts4 MESH and texture by Madlen Полигоны/Poly: 5536 Downloads: https://lindasims2.wixsite.com/lindasims2/product-page/af-bottom-madlen-porticishoes-24swatches
64 notes · View notes
Text
Spread Betting - How To Get Poor Quickly?
Tumblr media
As I write this, I'm nursing a bit of a sore head and an empty wallet. In the last four weeks I've lost almost £30,000 spread betting for about an hour a day five days a week. So I managed to blow around £1,500 an hour. That's really quite a chunk of cash. Actually, it's not quite as bad as it looks. Fortunately, I was betting using a few spread-betting companies' demo sites. These are simulations of their live betting sites that allow you to practice before you start betting with real money. I realise that I am no financial genius otherwise I would have been rich long ago. However, the fact that I managed to squander so much money so quickly does pose the question - if spread betting seems so easy, why do so many people get completely wiped out extremely quickly?
We're increasingly seeing advertising for spread betting in investing and money management publications. In the one I subscribe to, four or five different spread betting companies take full-page colour ads each week, outnumbering any other type of advertising. Spread betting ads are already common in the business sections of many weekend newspapers and will probably soon start to appear in the personal finance sections. Spread betting could appear deceptively attractive to many savers. After all, money in a bank, shares or unit trusts will at best give us about a miserable five per cent a year before tax. Yet a reasonable run on spread betting can easily let you pocket ten per cent a week - five hundred per cent a year - completely and gloriously tax-free. So spread betting can let you earn in just one year what it would take a hundred years or more to achieve with most other investments.
Spread betters gamble on price movements of anything from individual shares, currencies and commodities to whole markets like the FTSE, Dax or S&P. It is called spread betting because the company providing the service makes most of their money by putting an additional spread around the price at which something is being bought or sold.
Spread betting appears to have many advantages compared to traditional investing:
You don't have to buy anything - It allows you to bet on price movements without having to buy the underlying assets - shares, commodities or foreign exchange.
It's tax-free - When you buy or sell shares, get paid dividends or receive interest from a bank you will have to pay taxes like stamp duty, capital gains and income tax. Unless spread betting is your full-time job and only source of income, there are no taxes to be paid as it's considered to be gambling.
You can go long or short - When you spread bet you can gain just as much whether prices rise or fall, providing you guess the direction correctly. With most other investments, you need the price to go up before you make a profit.
You can bet on a rise or fall at the same time - If the FTSE, for example, is trading at 5551-5552, you can place two bets, one that it will rise and one that it will fall. These only get triggered when the FTSE actually moves. So if it starts going up, your bet that it will rise gets triggered. Similarly if it drops, only your bet that it will fall is triggered. So it can seem that, come rain or shine, you'll probably win.
Huge leverage - If you bet say £50 a pip (a pip is usually the minimum price movement you can bet on), you can easily win four or five times your original bet if the price moves in the right direction. On a really good bet, you can win much much more.
You can wait for the breakout - Prices on many shares, currencies, commodities and other things people bet on tend to experience periods of stability followed by bursts of movement up or down, what spread-betters call 'the breakout'. You can place a bet that is only activated when the breakout comes.
Loss limits - You can put conditions in your bet that prevent your losses exceeding your chosen level should your bet happen to be wrong.
You can adjust mid-flight - With most bets, such as with horse racing or on roulette, once the race has started or the croupier has called 'no more bets' you have to wait helplessly for the result to see if you've won or not. With spread betting you can choose to close your bet at any time. So if you're ahead, you can take your winnings; if you're behind you can either cut your losses or wait in the hope that things will change and you'll be up again. Given all these properties of spread betting, it should be pretty easy to make a fair bit of money without too much effort. If only.
Industry estimates suggest that around ninety per cent of spread-betters lose most or all of their money and close their accounts within three months of starting. There seem to be another eight per cent or so who make reasonable amounts of money on a regular basis and there are around two per cent of spread-betters who make fortunes. I've been to a few presentations run by spread betting companies and at one of these the salesman let slip that over eighty per cent of his customers lost money. Even many professionals lose on about six bets out of every ten. But by controlling their losses and maximising their returns when they win, they can increase their wealth.
Why it can go horribly wrong
There seem to be several reasons why spread betting is so effective at dramatically demolishing most practitioners' wealth:
The companies want you to lose - When you first open a demo or real account, you will get several phone calls from extremely friendly and helpful young men and women at the spread-betting company asking if there's anything they can do to assist you to get going. This is customer service at its very best. Most of the people contacting you will parrot the line that they just want to help and that they're happy if you're successful as their company only makes money from the spread. Some will reassure you that they want you to win as the more you win, the more you're likely to bet and the more the spread-betting company will earn. This may make you feel good, convince you that the company is open, honest, trustworthy and supportive and encourage you to use them for your betting. But it's also a lie. It's true that the company might make a lot of its money from the spread. However, with many of your bets, you're betting against the company and so they hope you lose, big time. In fact, during the last month I've seen several companies change the conditions on their sites to make it more likely that people using them will lose. So, lesson one - spread betting companies are not your friends. The more you lose the more they win. It's that simple.
It's difficult to break even - If you bet say £50 a pip and the price does go the way you want, the spread betting company takes the first £50 you win. So the price has to move two pips in the right direction for you to win your £50 back and three pips for you to emerge with £100, doubling your money. But if the price moves three pips in the wrong direction, you lose your original bet plus £50 a pip, giving a total loss of £200, a loss of four times your original bet.
Losses can be massive - With most gambling, you can only lose what you put down on a horse, blackjack or roulette. With spread betting you can quickly say goodbye to much more than you wager. I forgot to put a stop loss on one bet and managed to lose over £800 with just one £50 bet. Because your bet is leveraged, you can make both fabulous gains and excruciatingly painful losses. Too often it's the latter. The small size of many bets, often £5 or £10 a pip can lull betters into a false sense of security. It's only when the losses go five to ten times the original bet that they realise the risk they have taken. "The spread betting leverage means that you can get rich which is a wonderfully appealing idea, but it also means you can get poor which most people ignore."
You can waste thousands on courses and systems - At one free spread-betting seminar I attended we were more than strongly encouraged to sign up for a two-day weekend course teaching us how to spread bet successfully. This would normally cost (we were told) £6,995, but there was a special offer for the first five people to sign up of only £1,997. There are many such courses and also gurus offering to sell you their special spread-betting systems, guides, webinars and all sorts of other advice. With so many supposed experts apparently making a living teaching others how to spread bet, there must be a lot of takers. But I've found that all you need to know and more is available free on the Internet. As one specialist said, 'Don't bother wasting your money on 'Guru' books written by so-called experts. Those books are crap and not worth the paper they are printed on. Nobody sells a secret trading methodology if they are really successful. The only reason these guys are writing books is because they didn't make it as traders'.
It's the bobbing about that beats you - We often hear on the news that the price of gold has risen by a few dollars an ounce or the FTSE has fallen by a hundred and thirty points or that the pound has risen by two cents against the dollar. These reports make price changes on financial instruments sound like smooth movements either up or down. However, the prices of shares, stock markets, commodities and currencies seldom move in straight lines. They jump about every few seconds. So, if the FTSE is at 5540 and you correctly bet £50 a pip that it will go up to 5545 you might not necessarily win £200. In between going from 5540 to 5545, it might drop down a couple of times to say 5535 or lower. If you have a stop loss on at 5536 or 5535 to avoid losing too much money, your stop loss will kick in and you'll lose £250 or £300 even if the index did subsequently move upwards as you predicted. I've placed over a hundred bets to test whether I won when my bets were right. On about eighty per cent I lost in spite of being right because the fluctuations triggered the stop losses even though the index did actually move from where it was to where I predicted it would go. This creates a rather odd situation where stop losses can unfortunately make you lose even when you should be winning. Yet if you don't put stop losses on and things go in the wrong direction, your losses can annihilate you.
It attracts losers - At the spread betting seminars I've attended, I've been shocked by the number of low-paid workers - waiters, porters, kitchen staff, healthcare assistants and impoverished, would-be writers like myself - who decide to have a go at spread betting as they believe that, apart from winning the Lottery, it may be the only realistic way they have of making any money. These people will be betting with their meagre life savings against extremely sophisticated financial services insiders with vast knowledge, many years experience and extraordinarily deep pockets. It's not difficult to guess who is going to win.
Sucker or smartie?
Spread betting is a 'zero sum game'. Unlike depositing our money in a bank so it can be lent to businesses or house-buyers, spread betting doesn't create wealth. It just redistributes money from the suckers to the smart. When contemplating whether to try your hand at spread betting, you need to work out whether you are likely to be in the ninety per cent who end up as suckers or the ten per cent who make money by being smart. I found it interesting that not a single one of the amiable young men and women from spread-betting companies that I spoke to actually did any spread betting themselves. By the way, when I did eventually open a live spread betting account and managed to win about £100 a day for ten days, the spread betting company started preventing me getting out of losing bets because they claimed I was "betting unfairly". However, if you do manage to spread bet successfully, please drop me an email, I'd love to find out how to do it sakong online.
1 note · View note
playbest · 2 years
Text
Obtain Profitable No Deposit Bonus in Slottica Casino 2022!
Tumblr media
The Slottica Casino: Special Offers for Players! The licensed casino always has the most interesting offers. The Slottica casino (Curacao 5536/JAZ) is a perfect example of such a casino where you can play with real dealers, get tons of different bonuses and participate in lotteries and tournaments. All services can be used only by adults. Slottica Casino (New Review 2021): Get 50FS in Starburst (No Deposit)! No Deposit Bonuses from the Slottica Casino! When you finish the registration at Slottica Casino you will get the first offer: 50 free spins for Starburst with 5 RUB (0,01 EUR/0,3 PLN) bets. This is a no deposit bonus so you do not need to make any deposits to activate it. The only requirement is to verify your phone number and email address. Once you’ve used up the bonus it needs to be wagered with x45 wager and only then you will be able to withdraw up to 300 RUB/2 EUR/9 PLN. Get Bonus! The official site "Slottica Casino" and mirror sites! The site "Slottica Casino" looks really clean and neat: a plain white background that makes banners stand out. The interface is really user-friendly so any player can easily adapt to the site. Game-machine, live casino, promotion and calendar sections are located right next to the logo. The main page has some games from the game collection and the footer contains all the information. Bonus System of Slottica Casino There are several kinds of bonuses to make your gambling that much beneficial. First, you get a welcome package: ● Extra 200% to your first deposit form 300 RUB (15 EUR/70 PLN); ● 30 free spins for Gonzo’s Quest for the second replenishment from 3 000 RUB (40 EUR/170 PLN); ● Extra 100% to your third deposit from 5 000 RUB (85 EUR/350 PLN). ● All the lists bonuses have x45 wager. Bonus System of Slottica You can activate even more bonuses for a deposit from 6 000 RUB (85 EUR/360 PLN). If you do that you will be getting 25 free spins with x1 wager a day for 5 days straight. Get Bonus! Lotteries and Tournaments. The casino Slottica carries out themed activities every week. Competitive players can join the “Australian Adventure” with the 100 000 RUB (1 400 EUR/5 900 PLN) prize fund. There will be only 100 winners, so we expect the battle to be really intense. If you are a calm gambler you can take part in a lottery. Participation is free of charge and you only need to replenish your account by an amount that is indicated in conditions. Game collection of Slottica Casino The game collection of Slottica Casino consists of different kinds of slots, roulette, baccarat, poker and blackjack from the most prominent gaming software providers including: - Playtech (Iron Man), - Novomatic (Illusionist), - NetEnt (Dead Or Alive), - BetSoft (The SlotFather II) etc. You can go ahead and use demo-mode to try out games and learn their peculiarities. Use the sorting feature to find your favourite game as soon as possible. Games and Providers in Slottica Casino Play! There is a special live casino category for real gambling enthusiasts. You get to interact with real dealers but you can only play for real money since live casino games do not have demo-mode in Slottica Casino. Slottica Live Casino. Financial Operations. If you want to play for money you need to make a deposit in Slottica Casino. You can choose any available payment method at your will (ecoPayz, Pay Giga, Visa, Qiwi, Jeton, Neteller, MasterCard, Skrill etc). Minimum deposit amount is 100 RUB (2 EUR/5 PLN) and the least you can withdraw is 150 RUB (2 EUR/5 PLN). Withdrawal requests are accepted provided you do not have unwagered bonuses and you have passed verification. Requests are processed within 36 hours. If you are in search of a casino where you do not need to worry about security you have just found it. Sign up to the Slottica Casino and enjoy the huge game collection, regular themed activities and various bonuses that will bring you big winnings. Play! Slottica Casino Review Play! Playbestcasino.net Слоттика Казино: Обзор на Русском! Slottica казино: Забери 50 Вращений Без Депозита (Фриспины) + Бонусы! Playbestcasino.net Home Read the full article
0 notes
Photo
Tumblr media
Penn Libraries Schimmel Fiction 5536: Title page https://ift.tt/3JLLoPS
0 notes
songwriternews · 3 years
Text
New Post has been published on SONGWRITER NEWS
New Post has been published on https://songwriternews.co.uk/2021/04/beautiful/
Beautiful
Tumblr media Tumblr media
https://audio-ssl.itunes.apple.com/itunes-assets/Music3/v4/59/54/ec/5954ec7d-d24d-5536-886c-0aaa5aacd966/mzaf_3900804074512313596.plus.aac.p.m4a
By Doja Cat
Download now from Itunes
All of the Artists Featured on our pages are already getting lots of publicity everywhere!
Emerging Songwriters & Artists – Songwriter News has evolved into a slick robust music press platform with a smart trendy multi-platform adaptive appearance and an increasing level of site traffic which numbers approx 30,000 page views per week – circa 120,000+ page views per month.
Fans and followers – Get access to the Latest upcoming hits and stars before everyone else ! – Artists and Songwriters get your music in front of our fast growing audience !! 
Now Independent songwriters and artists have access to our platform via our online Press-Room where it is possible to create your very own press release and run a campaign to gain the attention of industry, fans, followers and other site visitors.Find out more by clicking on Press Room in the menu above. Businesses – Studios, Producers , Music Coaches Event Organisers – We have a place for you on our pages too – Click on the Advertising section to see our banner advertising rates and Find Your tribe with SongwriterNews.
Tumblr media
0 notes
jimmieespi · 3 years
Text
Ut a turpis at risus fringilla tincidunt placerat non orci
Law enforcement are interrogating the suspect, although they have not detained anybody.
I talked to Joe and Alex about WordAi today.
Nunc et mauris purus. In scelerisque libero vel turpis imperdiet auctor. Aliquam pellentesque purus sed ante elementum tempor. Cras accumsan tellus at tortor vestibulum rutrum. Mauris sit amet bibendum tellus, tristique iaculis sapien. Aliquam sit amet sem eget felis suscipit tincidunt. Vestibulum fermentum condimentum malesuada. Nullam tellus lectus, finibus in ex id P Prayer Journal For Men Lined Blank Pages With Qu 1, venenatis aliquet lectus. Cras pretium pretium purus, non luctus lectus pulvinar non. Sed nec neque at mi finibus luctus sit amet in lectus. Integer sodales fringilla sapien rutrum egestas. Fusce interdum convallis dolor. In ac erat ullamcorper, pharetra elit quis, iaculis risus. Donec ultrices sapien vitae consectetur elementum. In id sem vel nisl vulputate tempor.
Nunc urna nisi, volutpat vel enim non, sollicitudin auctor purus. Nam in mattis sem. Fusce non ultricies neque. Duis egestas magna eget finibus auctor. Praesent euismod iaculis velit quis interdum. Nulla ultricies magna non elit volutpat sagittis IrtSGzAuZt Kinslayer Gotrek Amp Felix. Mauris diam ligula, pharetra quis ipsum pharetra, bibendum congue orci. Maecenas aliquet, ipsum mollis lacinia lobortis, velit tellus lobortis odio, nec consectetur tellus mauris convallis nisl.
Duis hendrerit, nisl sed imperdiet consectetur, erat velit dignissim lacus, nec pretium enim tellus quis ex.
Integer rhoncus nunc sed turpis tincidunt vulputate 075mrMykHpo Discombobulated Fun With Phonetics Paperback. Nullam fermentum sapien eu risus sodales maximus. In vel commodo ex. Ut a turpis at risus fringilla tincidunt placerat non orci. Donec viverra, risus sit amet aliquam dapibus, est purus dictum velit, eu scelerisque lectus nibh ac sapien. In sem massa, tincidunt eu lorem eleifend, rhoncus tincidunt augue. Integer porta nunc nec nisi maximus, sed volutpat leo bibendum. Proin suscipit tortor leo, sit amet tempus velit ultrices et. Fusce aliquet mauris nisl, non euismod augue mollis ultrices. Pellentesque eu lectus elit.
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Duis tempus ut sapien condimentum fringilla. Mauris commodo felis nec egestas rutrum. Donec semper convallis libero, mollis malesuada NcaReEhzHPg The Bluetick Coonhound A Complete And Comprehens nibh ullamcorper interdum. Nullam eget nisi pharetra, posuere arcu non, aliquet sapien. Curabitur blandit condimentum lacus quis consectetur. In quis hendrerit sem. Donec laoreet velit nisi, id pellentesque sapien lacinia facilisis. Nunc ut scelerisque risus, at sollicitudin leo. Pellentesque nulla massa, ornare nec interdum sed, rutrum vel dui. Integer vestibulum quam in lacus eleifend, in porta nisi sodales. Nullam vehicula rhoncus lorem eu fermentum. Proin ut feugiat ex. Morbi consequat nulla ipsum.
0 notes
stephenespin · 3 years
Text
Mauris sit amet bibendum tellus, tristique iaculis sapien
Lorem ipsum dolor sit amet, consectetur adipiscing elit. Duis tempus ut sapien condimentum fringilla. Mauris commodo felis nec egestas rutrum. Donec semper convallis libero, mollis malesuada R Realistic Cost Estimating For Manufacturing Hard nibh ullamcorper interdum. Nullam eget nisi pharetra, posuere arcu non, aliquet sapien. Curabitur blandit condimentum lacus quis consectetur. In quis hendrerit sem. Donec laoreet velit nisi, id pellentesque sapien lacinia facilisis. Nunc ut scelerisque risus, at sollicitudin leo. Pellentesque nulla massa, ornare nec interdum sed, rutrum vel dui. Integer vestibulum quam in lacus eleifend, in porta nisi sodales. Nullam vehicula rhoncus lorem eu fermentum. Proin ut feugiat ex. Morbi consequat nulla ipsum.
Duis hendrerit, nisl sed imperdiet consectetur, erat velit dignissim lacus, nec pretium enim tellus quis ex.
Integer rhoncus nunc sed turpis tincidunt vulputate QYMxyhku06 Slocum And The Teamster Lady Paperback. Nullam fermentum sapien eu risus sodales maximus. In vel commodo ex. Ut a turpis at risus fringilla tincidunt placerat non orci. Donec viverra, risus sit amet aliquam dapibus, est purus dictum velit, eu scelerisque lectus nibh ac sapien. In sem massa, tincidunt eu lorem eleifend, rhoncus tincidunt augue. Integer porta nunc nec nisi maximus, sed volutpat leo bibendum. Proin suscipit tortor leo, sit amet tempus velit ultrices et. Fusce aliquet mauris nisl, non euismod augue mollis ultrices. Pellentesque eu lectus elit.
Nunc et mauris purus. In scelerisque libero vel turpis imperdiet auctor. Aliquam pellentesque purus sed ante elementum tempor. Cras accumsan tellus at tortor vestibulum rutrum. Mauris sit amet bibendum tellus, tristique iaculis sapien. Aliquam sit amet sem eget felis suscipit tincidunt. Vestibulum fermentum condimentum malesuada. Nullam tellus lectus, finibus in ex id 762mds24IiJ Shadowblack Two In The Page Turning New Fan 1, venenatis aliquet lectus. Cras pretium pretium purus, non luctus lectus pulvinar non. Sed nec neque at mi finibus luctus sit amet in lectus. Integer sodales fringilla sapien rutrum egestas. Fusce interdum convallis dolor. In ac erat ullamcorper, pharetra elit quis, iaculis risus. Donec ultrices sapien vitae consectetur elementum. In id sem vel nisl vulputate tempor.
Nobody is detained by the police officers, but the defendant has been interrogated by them.
I talked to Alex and Joe about WordAi today.
Praesent dapibus elementum nunc ZjtzCUUZ History A Very Short Introduction Paperback, nec eleifend magna consequat porta. Morbi vitae felis efficitur, ultrices tellus quis, sagittis nisl. Vivamus gravida urna eget sem vehicula maximus ornare in felis. Aliquam massa urna, tempor nec erat vitae, sodales semper ipsum. Aenean interdum est et tortor facilisis sagittis. Aenean aliquam dictum eros, ac tempus tellus sollicitudin vitae. Donec vitae sapien ac leo dictum laoreet. Mauris tincidunt urna justo, sed aliquam nulla aliquet sit amet. #####Integer in erat vitae tortor suscipit hendrerit eu et urna. Nam et neque hendrerit, bibendum ligula non, malesuada lectus.
0 notes
goattrain · 7 years
Photo
Tumblr media
Full-color commission for Croc Creator!
Their big gnoll lady relaxing after a big day.  I don’t often draw destructive scenes like this, but I’m trying to expand my horizons a little bit.  We’ll see if this is a trend I can continue with, or if I end up needing to back down, haha.
The full-resolution image and .sai project file can be found on my Patreon page!
Also in the fun last night, I neglected to realize I passed my 4300th post!  So as I do every 100 posts, it’s time to gather a little bit of data on the blog.  Data will be presented in a (past total + current period = new total) format.
Posts:  4200 + 106 = 4306
Followers:  5536 + 126 = 5665
Date Began:  September 11, 2012
Current Date:  November 2, 2017
Elapsed Time:  ~62 months
Total Pictures Posted:  7289 + 144 = 7433
Unique Pictures Posted:  6554 + 137 = 6691
Non-Art Posts:  702 + 6 = 708
119 notes · View notes
deunoposteoficial · 4 years
Text
Look Loterias 18 Horas 10/11/2020 – Resultado Jogo do Bicho Goiás
Resultado Jogo do Bicho da Look Loterias de hoje das 18 horas:
PrêmioResultadoGrupo1º132306 – CABRA2º560502 – ÁGUIA3º859023 – URSO4º553609 – COBRA5º884812 – ELEFANTE
Soma: 29902
Super 5: 12 18 08 09 22
<style> .information{padding:20px 10px!important} a{color: #00597a;} table { margin: 0 auto; width: 100%; display: inline-table; background: #f9f9f9; border-top: 0px; font-size: 13px; overflow: hidden; text-align: left; } td{} tr:nth-child(even) {background: #fff} tr:nth-child(odd) {9} th, td { padding: 8px; } td {border-bottom:0px solid!important;} th, td{border:0px} thead{font-size: 13px; text-transform: uppercase; background: #909090; color: #f3f3f3;} tfoot{border-right: 1px solid #909090; background: #eee; border-top: 1px solid #909090; display: block;font-size: 12px; } .pull-left { float: left!important; } .pull-right { float: right!important; } figure { margin: 0px 0px!important; border: 1px solid #909090!important; box-shadow: 0px 5px 7px #ccc;} h3 { font-size: 1.8rem; background: black; color: #fff; padding: 5px; margin-bottom: 0px; } p{padding: 0px 10px;} h2{padding: 0px 10px;font-size:20px!important} a {text-decoration:none;} page-moblets-list-detail .content p { font-size: 13px;} </style>
source https://resultadodojogodobicho.deunoposte.online/look-loterias-18-horas-10-11-2020-resultado-jogo-do-bicho-goias/
0 notes
casino123aft · 4 years
Text
Spread Betting - How To Get Poor Quickly?
As I write this, I'm nursing a bit of a sore head and an empty wallet. In the last four weeks I've lost almost £30,000 spread betting for about an hour a day five days a week. So I managed to blow around £1,500 an hour. That's really quite a chunk of cash. Actually, it's not quite as bad as it looks. Fortunately, I was betting using a few spread-betting companies' demo sites. These are simulations of their live betting sites that allow you to practice before you start betting with real money. I realise that I am no financial genius otherwise I would have been rich long ago. However, the fact that I managed to unibet casino svenska squander so much money so quickly does pose the question - if spread betting seems so easy, why do so many people get completely wiped out extremely quickly?
Tumblr media
We're increasingly seeing advertising for spread betting in investing and money management publications. In the one I subscribe to, four or five different spread betting companies take full-page colour ads each week, outnumbering any other type of advertising. Spread betting ads are already common in the business sections of many weekend newspapers and will probably soon start to appear in the personal finance sections. Spread betting could appear deceptively attractive to many savers. After all, money in a bank, shares or unit trusts will at best give us about a miserable five per cent a year before tax. Yet a reasonable run on spread betting can easily let you pocket ten per cent a week - five hundred per cent a year - completely and gloriously tax-free. So spread betting can let you earn in just one year what it would take a hundred years or more to achieve with most other investments.
Spread betters gamble on price movements of anything from individual shares, currencies and commodities to whole markets like the FTSE, Dax or S&P. It is called spread betting because the company providing the service makes most of their money by putting an additional spread around the price at which something is being bought or sold.
Spread betting appears to have many advantages compared to traditional investing:
You don't have to buy anything - It allows you to bet on price movements without having to buy the underlying assets - shares, commodities or foreign exchange.
It's tax-free - When you buy or sell shares, get paid dividends or receive interest from a bank you will have to pay taxes like stamp duty, capital gains and income tax. Unless spread betting is your full-time job and only source of income, there are no taxes to be paid as it's considered to be gambling.
You can go long or short - When you spread bet you can gain just as much whether prices rise or fall, providing you guess the direction correctly. With most other investments, you need the price to go up before you make a profit.
You can bet on a rise or fall at the same time - If the FTSE, for example, is trading at 5551-5552, you can place two bets, one that it will rise and one that it will fall. These only get triggered when the FTSE actually moves. So if it starts going up, your bet that it will rise gets triggered. Similarly if it drops, only your bet that it will fall is triggered. So it can seem that, come rain or shine, you'll probably win.
Huge leverage - If you bet say £50 a pip (a pip is usually the minimum price movement you can bet on), you can easily win four or five times your original bet if the price moves in the right direction. On a really good bet, you can win much much more.
You can wait for the breakout - Prices on many shares, currencies, commodities and other things people bet on tend to experience periods of stability followed by bursts of movement up or down, what spread-betters call 'the breakout'. You can place a bet that is only activated when the breakout comes.
Loss limits - You can put conditions in your bet that prevent your losses exceeding your chosen level should your bet happen to be wrong.
You can adjust mid-flight - With most bets, such as with horse racing or on roulette, once the race has started or the croupier has called 'no more bets' you have to wait helplessly for the result to see if you've won or not. With spread betting you can choose to close your bet at any time. So if you're ahead, you can take your winnings; if you're behind you can either cut your losses or wait in the hope that things will change and you'll be up again. Given all these properties of spread betting, it should be pretty easy to make a fair bit of money without too much effort. If only.
Industry estimates suggest that around ninety per cent of spread-betters lose most or all of their money and close their accounts within three months of starting. There seem to be another eight per cent or so who make reasonable amounts of money on a regular basis and there are around two per cent of spread-betters who make fortunes. I've been to a few presentations run by spread betting companies and at one of these the salesman let slip that over eighty per cent of his customers lost money. Even many professionals lose on about six bets out of every ten. But by controlling their losses and maximising their returns when they win, they can increase their wealth.
Why it can go horribly wrong
There seem to be several reasons why spread betting is so effective at dramatically demolishing most practitioners' wealth:
The companies want you to lose - When you first open a demo or real account, you will get several phone calls from extremely friendly and helpful young men and women at the spread-betting company asking if there's anything they can do to assist you to get going. This is customer service at its very best. Most of the people contacting you will parrot the line that they just want to help and that they're happy if you're successful as their company only makes money from the spread. Some will reassure you that they want you to win as the more you win, the more you're likely to bet and the more the spread-betting company will earn. This may make you feel good, convince you that the company is open, honest, trustworthy and supportive and encourage you to use them for your betting. But it's also a lie. It's true that the company might make a lot of its money from the spread. However, with many of your bets, you're betting against the company and so they hope you lose, big time. In fact, during the last month I've seen several companies change the conditions on their sites to make it more likely that people using them will lose. So, lesson one - spread betting companies are not your friends. The more you lose the more they win. It's that simple.
It's difficult to break even - If you bet say £50 a pip and the price does go the way you want, the spread betting company takes the first £50 you win. So the price has to move two pips in the right direction for you to win your £50 back and three pips for you to emerge with £100, doubling your money. But if the price moves three pips in the wrong direction, you lose your original bet plus £50 a pip, giving a total loss of £200, a loss of four times your original bet.
Losses can be massive - With most gambling, you can only lose what you put down on a horse, blackjack or roulette. With spread betting you can quickly say goodbye to much more than you wager. I forgot to put a stop loss on one bet and managed to lose over £800 with just one £50 bet. Because your bet is leveraged, you can make both fabulous gains and excruciatingly painful losses. Too often it's the latter. The small size of many bets, often £5 or £10 a pip can lull betters into a false sense of security. It's only when the losses go five to ten times the original bet that they realise the risk they have taken. "The spread betting leverage means that you can get rich which is a wonderfully appealing idea, but it also means you can get poor which most people ignore."
You can waste thousands on courses and systems - At one free spread-betting seminar I attended we were more than strongly encouraged to sign up for a two-day weekend course teaching us how to spread bet successfully. This would normally cost (we were told) £6,995, but there was a special offer for the first five people to sign up of only £1,997. There are many such courses and also gurus offering to sell you their special spread-betting systems, guides, webinars and all sorts of other advice. With so many supposed experts apparently making a living teaching others how to spread bet, there must be a lot of takers. But I've found that all you need to know and more is available free on the Internet. As one specialist said, 'Don't bother wasting your money on 'Guru' books written by so-called experts. Those books are crap and not worth the paper they are printed on. Nobody sells a secret trading methodology if they are really successful. The only reason these guys are writing books is because they didn't make it as traders'.
It's the bobbing about that beats you - We often hear on the news that the price of gold has risen by a few dollars an ounce or the FTSE has fallen by a hundred and thirty points or that the pound has risen by two cents against the dollar. These reports make price changes on financial instruments sound like smooth movements either up or down. However, the prices of shares, stock markets, commodities and currencies seldom move in straight lines. They jump about every few seconds. So, if the FTSE is at 5540 and you correctly bet £50 a pip that it will go up to 5545 you might not necessarily win £200. In between going from 5540 to 5545, it might drop down a couple of times to say 5535 or lower. If you have a stop loss on at 5536 or 5535 to avoid losing too much money, your stop loss will kick in and you'll lose £250 or £300 even if the index did subsequently move upwards as you predicted. I've placed over a hundred bets to test whether I won when my bets were right. On about eighty per cent I lost in spite of being right because the fluctuations triggered the stop losses even though the index did actually move from where it was to where I predicted it would go. This creates a rather odd situation where stop losses can unfortunately make you lose even when you should be winning. Yet if you don't put stop losses on and things go in the wrong direction, your losses can annihilate you.
It attracts losers - At the spread betting seminars I've attended, I've been shocked by the number of low-paid workers - waiters, porters, kitchen staff, healthcare assistants and impoverished, would-be writers like myself - who decide to have a go at spread betting as they believe that, apart from winning the Lottery, it may be the only realistic way they have of making any money. These people will be betting with their meagre life savings against extremely sophisticated financial services insiders with vast knowledge, many years experience and extraordinarily deep pockets. It's not difficult to guess who is going to win.
0 notes
wallpapernifty · 4 years
Text
23 Thoughts You Have As Rosebud Flower Girl Dresses Approaches | Rosebud Flower Girl Dresses
With June 21 fast approaching, the admission to Father’s Day is on.
Tumblr media
Rosebud Fashions 5115 Flower Girl Dress | MadameBridal | rosebud flower girl dresses
Whether you alive calm or haven’t apparent him aback lockdown began, this year there’s added acumen than anytime to amusement your old man and appearance him how abundant you care.
The agitation is, dads can be awfully catchy to boutique for. While there are the trad man ability of cufflinks, socks and ties, your pa deserves article more, article bigger – and we accept aloof the thing; aliment and alcohol gifts.
Tumblr media
Rosebud Fashions Flower Girl Dresses Style 23 – Organza & Horsehair Trim – rosebud flower girl dresses | rosebud flower girl dresses
Because if there’s one affair affirmed to put a smile on his chops, it’s a aftertaste or sip of article he loves. It could be a canteen of article special, a trunkle of that absolutely stinky, gourmet cheese he inexplicably loves or a boozy bassinet for him to admire all to himself. Accept any of these options safe in the ability that there’s aught adventitious of them acquisition dust on an abhorred shelf somewhere.
From chic hampers abounding with treats to sippin’ whisky he can savour through the summer, actuality are our favourite ability that he can bore his teeth into.
Tumblr media
Flower Girl Dress Style #23 – rosebud flower girl dresses | rosebud flower girl dresses
See our favourites below
There’s few things best dads adulation than a quiet pint. Accomplish his day with this crate of 12 ability beers (think IPA, pilsner and ales) forth with a appropriate tasting canteen – all for a appropriate £30.
Tumblr media
Rosebud Flower Bow Ribbons Little Girl Flower Girls Dresses – Navy .. | rosebud flower girl dresses
Shipped anon to his aperture in ‘dad-proof packaging’ Beer Hawk has included a characterization
23 Thoughts You Have As Rosebud Flower Girl Dresses Approaches | Rosebud Flower Girl Dresses – rosebud flower girl dresses | Delightful in order to my personal blog, on this time period I am going to provide you with in relation to keyword. And now, this is the primary picture:
Tumblr media
Rosebud Fashions Flower Girl Dress Style 5132 & Bella .. | rosebud flower girl dresses
What about graphic above? can be which remarkable???. if you feel therefore, I’l t explain to you a number of photograph yet again below:
So, if you desire to get these fantastic pics related to (23 Thoughts You Have As Rosebud Flower Girl Dresses Approaches | Rosebud Flower Girl Dresses), just click save button to save the images to your laptop. They are ready for save, if you’d prefer and wish to have it, simply click save symbol on the page, and it will be instantly saved in your laptop.} As a final point if you need to secure new and the latest photo related to (23 Thoughts You Have As Rosebud Flower Girl Dresses Approaches | Rosebud Flower Girl Dresses), please follow us on google plus or book mark this site, we attempt our best to provide daily update with fresh and new photos. Hope you love staying right here. For some upgrades and latest news about (23 Thoughts You Have As Rosebud Flower Girl Dresses Approaches | Rosebud Flower Girl Dresses) images, please kindly follow us on tweets, path, Instagram and google plus, or you mark this page on bookmark section, We try to offer you up grade regularly with all new and fresh pictures, enjoy your surfing, and find the ideal for you.
Thanks for visiting our site, articleabove (23 Thoughts You Have As Rosebud Flower Girl Dresses Approaches | Rosebud Flower Girl Dresses) published .  At this time we’re delighted to announce that we have found an awfullyinteresting topicto be discussed, that is (23 Thoughts You Have As Rosebud Flower Girl Dresses Approaches | Rosebud Flower Girl Dresses) Many individuals attempting to find info about(23 Thoughts You Have As Rosebud Flower Girl Dresses Approaches | Rosebud Flower Girl Dresses) and certainly one of them is you, is not it?
Tumblr media
Tip Top 5536 Flower Girls Short Sleeve Dress – French Novelty – rosebud flower girl dresses | rosebud flower girl dresses
Tumblr media
Rosebud Organza Girl Dress – rosebud flower girl dresses | rosebud flower girl dresses
Tumblr media
Communion Veil with Crown $18.99 | Crowns with Veils .. | rosebud flower girl dresses
Tumblr media
Rosebud Fashions Flower Girl Dress Style 23 | House of Brides – rosebud flower girl dresses | rosebud flower girl dresses
Tumblr media
Rachel Allan Perfect Angels 1642 Girls Beaded Tulle .. | rosebud flower girl dresses
Tumblr media
White Orange Rosebud Flower Girl Dress Tiebow Sash Pageant Wedding .. | rosebud flower girl dresses
Tumblr media
Red Rosebud Detail Tulle Overlaid Lovely Flower Girl Dress – rosebud flower girl dresses | rosebud flower girl dresses
Tumblr media
Rosebud Fashions 23 Flower Girls Ruched Dress – rosebud flower girl dresses | rosebud flower girl dresses
Tumblr media
Off White Sleeveless Rosebud Flower Girl Dress with .. | rosebud flower girl dresses
Tumblr media
Flower Girl Dress – rosebud flower girl dresses | rosebud flower girl dresses
Tumblr media
Ivory Sleeveless Rosebud Texture Flower Girl Dress – rosebud flower girl dresses | rosebud flower girl dresses
Tumblr media
White Coral Rosebud Flower Girl dress sash by ekidsbridalusa – rosebud flower girl dresses | rosebud flower girl dresses
Tumblr media
Rachel Allan Perfect Angels 1606 Girls Chiffon Ball Gown .. | rosebud flower girl dresses
Tumblr media
RoseBud 23 Flower Girl Dress – rosebud flower girl dresses | rosebud flower girl dresses
Tumblr media
Smocked Easter Dress Light Blue w/ embroidery Handmade .. | rosebud flower girl dresses
Tumblr media
RoseBud 23 Flower Girl Dress – rosebud flower girl dresses | rosebud flower girl dresses
Tumblr media
Rosebud Fashions Flower Girl Dress Style 23 – rosebud flower girl dresses | rosebud flower girl dresses
Tumblr media
Rosebud 5106 Flower Girl Dress Dupioni Sash – rosebud flower girl dresses | rosebud flower girl dresses
from Wallpaper Nifty https://www.flowernifty.com/23-thoughts-you-have-as-rosebud-flower-girl-dresses-approaches-rosebud-flower-girl-dresses/
0 notes
chemwhat · 4 years
Text
SODIUM METHACRYLATE CAS#: 5536-61-8
IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data
Identification
Product NameSODIUM METHACRYLATE IUPAC Namesodium;2-methylprop-2-enoateMolecular Structure
Tumblr media
CAS Registry Number 5536-61-8EINECS Number226-896-5 MDL NumberMFCD00045886 Synonymssodium methacrylate, methacrylic acid sodium salt, sodium methylmethacrylate, sodium 2-methacrylate, Sodium methacrylate, sodium metacrylate, SMA Molecular FormulaC4H5NaO2 Molecular Weight108.07 InChIInChI=1S/C4H6O2.Na/c1-3(2)4(5)6;/h1H2,2H3,(H,5,6);/q;+1/p-1InChI KeySONHXMAHPHADTF-UHFFFAOYSA-MCanonical SMILESCC(=C)C(=O). Patent InformationPatent IDTitlePublication DateJP2016/196434 (Meth) acrylate-containing halogenated phosphate ester mixture and its manufacturing method, and a cured composition comprising a mixture of (by machine translation) 2016EP2100887 Lactone-containing compound, polymer, resist composition, and patterning process 2009US6346650 Method for making mixed high purity (meth)acrylic anhydrides 2002
Physical Data
AppearanceWhite superfine powder Water SolubilitySoluble in water. Metling Point 300°C Boiling Point100 °CDensity 2.703g/cm3@25°C
Spectra
Description (NMR Spectroscopy)Nucleus (NMR Spectroscopy)Solvents (NMR Spectroscopy)Temperature (NMR Spectroscopy), °C Frequency (NMR Spectroscopy), MHzChemical shifts1Hethanol-d640500.16 Description (IR Spectroscopy) Solvent (IR Spectroscopy)Bands potassium bromide SODIUM METHACRYLATE CAS 5536-61-8 IR
Tumblr media
Route of Synthesis (ROS)
Tumblr media
Route-of-Synthesis-ROS-of-SODIUM-METHACRYLATE-CAS-5536-61-8 ConditionsYieldWith sodium hydroxide In water; acetone Experimental Procedure Preparation of Sodium Methacrylate A 12.23 g (0.3058 mol) sample of sodium hydroxide was placed in a 50-ml Erlenmayer flask equipped with 10 ml water and a magnetic stirring bar, and the mixture was stirred to dissolution. The sodium hydroxide solution was then poured into a 250-ml beaker containing 30.70 g (0.3570 mol) methacrylic acid (exothermic reaction) with constant stirring. The mixture was allowed to cool, 50 ml of acetone were added, and the precipitate vacuum filtered. The recovered carboxylate salt was first allowed to air dry under a hood, and then dried in an oven at 55°-60° C. for 12-15 hours to afford 30.43 g (92.2percent yield) of sodium methacrylate.92.2%With sodium hydroxide Experimental Procedure Preparation of sodium methacrylate: After 5 kg (37.5 mol) of a 30percent aqueous solution of sodium hydroxide was cooled below 60° C., 3.23 kg (37.5 mol) of methacrylic acid was added drop by drop while stirring. The aqueous solution of sodium methacrylate obtained by the neutralization reaction was spray-dried with 300° C. hot air to yield 4.04 kg of a dry powder of sodium methacrylate. The water content of this powder was 0.08percent. With sodium hydroxide In water at 20 - 50℃; for 2.5h; Product distribution / selectivity; Experimental Procedure Example 3; A. Preparation of Sodium Methacrylate Solution; To a five liter 4-neck round bottom flask fitted with a reflux condenser, thermocouple, and mechanical stirrer was charged 1500.11 grams of de-ionized water. To this was incrementally added a total of 511.63 grams (12.79 moles) of sodium hydroxide pellets. The addition rate was such that the pot temperature did not exceed 50° C. After the solution cooled to room temperature, 1115.40 grams (12.82 moles) of methacrylic acid was added over the course of 2.5 hours. The temperature of the reaction mixture was kept below 50° C. throughout the methacrylic acid addition. This preparation resulted in a clear, colorless solution containing 44.1percent by weight sodium methacrylate. With sodium methylate In methanol for 1.3h; Product distribution / selectivity; Experimental Procedure Example 5; This example illustrates the use of sodium methoxide as the neutralizing base. To a 500 ml 4-neck round bottom flask equipped with a reflux condenser, addition funnel, thermocouple and magnetic stirrer was charged 38.67 grams (0.45 moles) of methacrylic acid and 52.12 grams of methanol. To the addition funnel was charged 95.89 grams of a 25percent solution of sodium methoxide in methanol (23.97 grams of contained sodium methoxide, 0.44 moles, 98.6percent of theoretical). The sodium methoxide solution was slowly added to the methacrylic acid over a 1.3 hour period with vigorous stirring. Near the end of the addition the amount of formed solids made stirring difficult. After all of the sodium methoxide solution was charged, the addition funnel was rinsed with 17.53 grams of methanol. To the resulting thick slurry was added 3.21 grams of a 34percent aqueous solution of hexaethylguanidinium chloride solution (1.09 grams of contained hexaethylguanidinium chloride, 4.1 mmoles). This material was rinsed into the reaction flask with 7.58 grams of methanol. The methanol was removed by mildly heating the reaction slurry under vacuum. The remaining paste was further dried by heating in a vacuum oven at 90° C. and 125 mmHg overnight. The resulting dry solids were broken up with a spatula and the reaction flask fitted with a reflux condenser, thermocouple and mechanical stirrer. To the solids were added 0.192 grams (0.45 mmoles) of 4,4'-methylenebis(2,6-di-t-butylphenol), 0.081 grams (0.36mmoles) of butylated hydroxytoluene (BHT) and 131.58 grams (0.66 moles) of chloropropyltrimethoxysilane. The mixture was then heated to 110° C. for 3 hours. During this time the color of the reaction mixture changes from purple to yellow. Analysis of the final product by gas chromatograpy indicated that the crude reaction mixture contained 72.3percent of the desired gamma-methacryloxypropyltrimethoxysilane.
Safety and Hazards
Pictogram(s)
Tumblr media Tumblr media Tumblr media
SignalDangerGHS Hazard StatementsH302: Harmful if swallowed H311: Toxic in contact with skin H314: Causes severe skin burns and eye damage H315: Causes skin irritation H318: Causes serious eye damage H319: Causes serious eye irritation H332: Harmful if inhaled H335: May cause respiratory irritation Information may vary between notifications depending on impurities, additives, and other factors. Precautionary Statement CodesP260, P261, P264, P270, P271, P280, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P312, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P403+P233, P405, and P501 (The corresponding statement to each P-code can be found at the GHS Classification page.)
Other Data
TransportationNot dangerous goodsUnder the room temperature and away from lightHS Code294200StorageUnder the room temperature and away from lightShelf Life2 yearsMarket PriceNo data valiable Use PatternSODIUM METHACRYLATE CAS#: 5536-61-8 can be used as dispersing agent; SODIUM METHACRYLATE CAS#: 5536-61-8 can be used as coating materials. Sodium Methacrylate polymerization reaction to poly acrylic acid SODIUM METHACRYLATE CAS#: 5536-61-8 is a kind of poly anionic polymer dielectric, is a widely used and important chemicals. Read the full article
0 notes
youraufildespages · 4 years
Photo
Tumblr media
Bilan de décembre 2019: une fin d’année ralentie L'heure du bilan <h3>Bonjour les amis</h3> <h3> 13 </h3> livres lus <h3> 5536 </h3> Pages tournées <h3> 13 </h3> livre ajoutés à la Pal <h3>Ce qui fait donc un</h3> <h2>+ 0 à ma Pal!</h2> <h2>Mes coups de coeur</h2> <img width="311" height="499" src=" alt="" srcset=" 311w, 187w" sizes="(max-width: 311px) 100vw, 311px" /> <h3>J'ai beaucoup aimé</h3> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="229"> <meta itemprop="height" content="376"> <img data-attachment-id="32140" data-orig-file=" data-orig-size="624,1024" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="la-coupure-1250229" data-image-description="" data-medium-file=" data-large-file=" src=" width="229" height="376" data-original-width="229" data-original-height="376" itemprop=" title="la-coupure-1250229" alt="la-coupure-1250229" style="width: 229px; height: 376px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="234"> <meta itemprop="height" content="376"> <img data-attachment-id="31231" data-orig-file=" data-orig-size="351,564" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="le-reve-de-toinet-1238646" data-image-description="" data-medium-file=" data-large-file=" src=" width="234" height="376" data-original-width="234" data-original-height="376" itemprop=" title="le-reve-de-toinet-1238646" alt="le-reve-de-toinet-1238646" style="width: 234px; height: 376px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="247"> <meta itemprop="height" content="376"> <img data-attachment-id="28591" data-orig-file=" data-orig-size="329,499" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="everless" data-image-description="" data-medium-file=" data-large-file=" src=" width="247" height="376" data-original-width="247" data-original-height="376" itemprop=" title="everless" alt="everless" style="width: 247px; height: 376px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="234"> <meta itemprop="height" content="376"> <img data-attachment-id="31355" data-orig-file=" data-orig-size="351,564" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="le pensionnat de catherine" data-image-description="" data-medium-file=" data-large-file=" src=" width="234" height="376" data-original-width="234" data-original-height="376" itemprop=" title="le pensionnat de catherine" alt="le pensionnat de catherine" style="width: 234px; height: 376px;" /> </a> <!-- close group --> <!-- close row --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="491"> <meta itemprop="height" content="733"> <img data-attachment-id="31509" data-orig-file=" data-orig-size="250,373" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="x-ou-y-1244223" data-image-description="" data-medium-file=" data-large-file=" src=" width="491" height="733" data-original-width="491" data-original-height="733" itemprop=" title="x-ou-y-1244223" alt="x-ou-y-1244223" style="width: 491px; height: 733px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="461"> <meta itemprop="height" content="733"> <img data-attachment-id="31555" data-orig-file=" data-orig-size="628,1000" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"1"}" data-image-title="horemheb" data-image-description="" data-medium-file=" data-large-file=" src=" width="461" height="733" data-original-width="461" data-original-height="733" itemprop=" title="horemheb" alt="horemheb" style="width: 461px; height: 733px;" /> </a> <!-- close group --> <!-- close row --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="225"> <meta itemprop="height" content="352"> <img data-attachment-id="30824" data-orig-file=" data-orig-size="319,499" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="les vignes de sarah" data-image-description="" data-medium-file=" data-large-file=" src=" width="225" height="352" data-original-width="225" data-original-height="352" itemprop=" title="les vignes de sarah" alt="les vignes de sarah" style="width: 225px; height: 352px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="223"> <meta itemprop="height" content="352"> <img data-attachment-id="31644" data-orig-file=" data-orig-size="349,550" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"1559566855","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"1"}" data-image-title="chroniques-des-cinq-trones-moities-d-ame-1247750" data-image-description="" data-medium-file=" data-large-file=" src=" width="223" height="352" data-original-width="223" data-original-height="352" itemprop=" title="chroniques-des-cinq-trones-moities-d-ame-1247750" alt="chroniques-des-cinq-trones-moities-d-ame-1247750" style="width: 223px; height: 352px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="264"> <meta itemprop="height" content="352"> <img data-attachment-id="31905" data-orig-file=" data-orig-size="400,534" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="fanny cloutier 2" data-image-description="" data-medium-file=" data-large-file=" src=" width="264" height="352" data-original-width="264" data-original-height="352" itemprop=" title="fanny cloutier 2" alt="fanny cloutier 2" style="width: 264px; height: 352px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="232"> <meta itemprop="height" content="352"> <img data-attachment-id="31476" data-orig-file=" data-orig-size="330,500" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="killer t" data-image-description="" data-medium-file=" data-large-file=" src=" width="232" height="352" data-original-width="232" data-original-height="352" itemprop=" title="killer t" alt="killer t" style="width: 232px; height: 352px;" /> </a> <!-- close group --> <!-- close row --> <h4>Je vous ai retrouvé pour d'agréables rendez-vous</h4> <h3>J'ai déjà prévu de lire beaucoup de belles choses en janvier!</h3> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="238"> <meta itemprop="height" content="364"> <img data-attachment-id="31474" data-orig-file=" data-orig-size="348,533" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="la poussière du temps 4" data-image-description="" data-medium-file=" data-large-file=" src=" width="238" height="364" data-original-width="238" data-original-height="364" itemprop=" title="la poussière du temps 4" alt="la poussière du temps 4" style="width: 238px; height: 364px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="227"> <meta itemprop="height" content="364"> <img data-attachment-id="31498" data-orig-file=" data-orig-size="351,564" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="la-fontaine-aux-violettes-1242554" data-image-description="" data-medium-file=" data-large-file=" src=" width="227" height="364" data-original-width="227" data-original-height="364" itemprop=" title="la-fontaine-aux-violettes-1242554" alt="la-fontaine-aux-violettes-1242554" style="width: 227px; height: 364px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="251"> <meta itemprop="height" content="364"> <img data-attachment-id="31577" data-orig-file=" data-orig-size="400,581" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="la reine sous la neige" data-image-description="" data-medium-file=" data-large-file=" src=" width="251" height="364" data-original-width="251" data-original-height="364" itemprop=" title="la reine sous la neige" alt="la reine sous la neige" style="width: 251px; height: 364px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="228"> <meta itemprop="height" content="364"> <img data-attachment-id="31579" data-orig-file=" data-orig-size="502,800" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="la-petite-fille-du-phare-1017518" data-image-description="" data-medium-file=" data-large-file=" src=" width="228" height="364" data-original-width="228" data-original-height="364" itemprop=" title="la-petite-fille-du-phare-1017518" alt="la-petite-fille-du-phare-1017518" style="width: 228px; height: 364px;" /> </a> <!-- close group --> <!-- close row --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="319"> <meta itemprop="height" content="477"> <img data-attachment-id="31513" data-orig-file=" data-orig-size="305,456" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="le dernier magicien tome 2" data-image-description="" data-medium-file=" data-large-file=" src=" width="319" height="477" data-original-width="319" data-original-height="477" itemprop=" title="le dernier magicien tome 2" alt="le dernier magicien tome 2" style="width: 319px; height: 477px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="315"> <meta itemprop="height" content="477"> <img data-attachment-id="31581" data-orig-file=" data-orig-size="1000,1517" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="les-faits-et-gestes-de-la-famille-papillon-tome-2—les-prouesses-de-mamie-rose-1262477.jpg" data-image-description="" data-medium-file=" data-large-file=" src=" width="315" height="477" data-original-width="315" data-original-height="477" itemprop=" title="les-faits-et-gestes-de-la-famille-papillon-tome-2---les-prouesses-de-mamie-rose-1262477.jpg" alt="les-faits-et-gestes-de-la-famille-papillon-tome-2---les-prouesses-de-mamie-rose-1262477.jpg" style="width: 315px; height: 477px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="314"> <meta itemprop="height" content="477"> <img data-attachment-id="31580" data-orig-file=" data-orig-size="195,296" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="desorientee-1256168" data-image-description="" data-medium-file=" data-large-file=" src=" width="314" height="477" data-original-width="314" data-original-height="477" itemprop=" title="desorientee-1256168" alt="desorientee-1256168" style="width: 314px; height: 477px;" /> </a> <!-- close group --> <!-- close row --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="201"> <meta itemprop="height" content="316"> <img data-attachment-id="31645" data-orig-file=" data-orig-size="345,542" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="quand-on-ne-peut-oublier-1257047" data-image-description="" data-medium-file=" data-large-file=" src=" width="201" height="316" data-original-width="201" data-original-height="316" itemprop=" title="quand-on-ne-peut-oublier-1257047" alt="quand-on-ne-peut-oublier-1257047" style="width: 201px; height: 316px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="217"> <meta itemprop="height" content="316"> <img data-attachment-id="31650" data-orig-file=" data-orig-size="1764,2560" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="la sorcière oubliée" data-image-description="" data-medium-file=" data-large-file=" src=" width="217" height="316" data-original-width="217" data-original-height="316" itemprop=" title="la sorcière oubliée" alt="la sorcière oubliée" style="width: 217px; height: 316px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="210"> <meta itemprop="height" content="316"> <img data-attachment-id="31074" data-orig-file=" data-orig-size="351,527" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="des dieux et des boulettes" data-image-description="" data-medium-file=" data-large-file=" src=" width="210" height="316" data-original-width="210" data-original-height="316" itemprop=" title="des dieux et des boulettes" alt="des dieux et des boulettes" style="width: 210px; height: 316px;" /> </a> <!-- close group --> <a href=" border="0" itemprop="url"> <meta itemprop="width" content="316"> <meta itemprop="height" content="316"> <img data-attachment-id="31815" data-orig-file=" data-orig-size="340,340" data-comments-opened="1" data-image-meta="{"aperture":"0","credit":"","camera":"","caption":"","created_timestamp":"0","copyright":"","focal_length":"0","iso":"0","shutter_speed":"0","title":"","orientation":"0"}" data-image-title="Le-bagne-des-enfants" data-image-description="" data-medium-file=" data-large-file=" src=" width="316" height="316" data-original-width="316" data-original-height="316" itemprop=" title="Le-bagne-des-enfants" alt="Le-bagne-des-enfants" style="width: 316px; height: 316px;" /> </a> <!-- close group --> <!-- close row --> <h3>Et vous, quel est votre bilan?</h3>
0 notes