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chemwhat · 1 year

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1-(3-fluoro-4-nitrophenyl)ethanone CAS#: 72802-25-6

IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data Identification Product Name1-(3-fluoro-4-nitrophenyl)ethanoneIUPAC Name1-(3-fluoro-4-nitrophenyl)ethanone Molecular StructureCAS Registry Number 72802-25-6EINECS NumberMDL NumberMFCD13194365Beilstein Registry NumberSynonyms1-(3-Fluoro-4-nitrophenyl)ethanone72802-25-61-(3-Fluoro-4-nitrophenyl)ethan-1-one1-(3-Fluoro-4-nitro-phenyl)-ethanoneMFCD13194365SCHEMBL11248434DTXSID00608606ZINC80815645AKOS016008225SB38480AS-49951SY129721CS-0103300O10276EN300-18285433 inverted exclamation mark -Fluoro-4 inverted exclamation mark -nitroacetophenoneMolecular FormulaC8H6FNO3Molecular Weight183.14InChIInChI=1S/C8H6FNO3/c1-5(11)6-2-3-8(10(12)13)7(9)4-6/h2-4H,1H3 InChI KeyUHAATBAYLFRWMR-UHFFFAOYSA-N Canonical SMILESCC(=O)C1=CC(=C(C=C1)(=O))F Physical Data Appearancepale yellow solid Spectra 1-(3-fluoro-4-nitrophenyl)ethanone CAS#: 72802-25-6 HNMR Route of Synthesis (ROS) Route of Synthesis (ROS) of 1-(3-fluoro-4-nitrophenyl)ethanone CAS-72802-25-6 ConditionsYieldWith methanol; sodium tetrahydroborate at 0℃; for 1h;99%With sodium tetrahydroborate In methanol at 20℃; for 1h;99%With methanol; sodium tetrahydroborate at -10 - 0℃; for 0.333333h; Concentration; Reflux;75%With methanol; sodium tetrahydroborate at -10 - 0℃; for 0.333333h;75%Experimental Procedure 1.b Synthesis of Compound 4To a mixture of Compound 3 (1.9 g, 10.4 mmol) in MeOH (20 mL) at -10 C was added NaBH4(418 mg, 11 mmol) in portions. The mixture was stirred between -10 C to 0 C for 20 minutes, diluted with EtOAc (300 mL), washed with sat. NH4Cl aqueous solution, brine, dried (Na2SO4). Filtered and concentrated under reduced pressure. The residue was purified via FCC (silica gel, EtOAc/Hexane) to afford Compound 4 as a light yellow oil (1.44g, 75% yield).1H NMR (CDCl3, 400 MHz) δ: 8.06 (t, J = 8.4 Hz, 1H), 7.35 (d, J = 11.6 Hz, 1H), 7.30 (d, J = 11.6 Hz, 1H), 5.01-4.99 (m, 1H), 1.52 (d, J = 6.4 Hz, 3H) ppm. Safety and Hazards No data available Other Data DruglikenessLipinski rules componentMolecular Weight183.139logP1.952HBA1HBD0Matching Lipinski Rules4Veber rules componentPolar Surface Area (PSA)62.89Rotatable Bond (RotB)2Matching Veber Rules2 BioactivityQuantitative Results Toxicity/Safety PharmacologyQuantitative Results Use Pattern1-(3-fluoro-4-nitrophenyl)ethanone CAS#: 72802-25-6 is used as a pharmaceutical intermediate. Read the full article

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vapemarkdownusa · 4 years

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Hitt Go 1.8ml Disposable Pod Systems Device

our price: $4.99Retail Price:$10.00You Save:$5.01(50%)In Stock.

The HITT GO Disposable Pod System is an ultra-portable and compact disposable vape pen, encapsulating a 5% nicotine salt strength, 1.8mL prefilled capacity, and houses an integrated 280mAh battery that can fire at a 3.7V output to deliver soothing and refined vapors that is sure to please the palate.

Features: Measurements: 100mm by 20mm by 7mm Battery: 280mAh Battery Input Voltage: 3.7V Concentration: 50mg/ml Power Range: 7W to 12W E-Liquid Capacity: 1.8ml

Includes: 1 x Hitt Go 1.8ML 280mAh Prefilled Disposable Pod Device

#Hitt Go #Pod System #disposable vape pen #vape #e liquid #Blueberry Pomegranat #coils

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the-bluespirit · 2 years

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#miraculous ladybug #mledit #ladynoir #ladybug #chat noir #ml 5.01 #gifs #*#ml #ml spoilers

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andromedabeauty · 4 years

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chemwhat · 1 year

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1-(3-fluoro-4-nitrophenyl)ethanone CAS#: 72802-25-6

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earthquake-breaking-news · 5 years

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Moderate earthquake 5.01 mag, 18 km E of Little Lake, CA

Earthquake News on http://www.earthquakenewstoday.com/2019/08/22/moderate-earthquake-5-01-mag-18-km-e-of-little-lake-ca/

Moderate earthquake 5.01 mag, 18 km E of Little Lake, CA

A moderate earthquake with magnitude 5.01 (ml/mb) was reported near Ridgecrest, California City, Alta Sierra, United States on Thursday. The temblor was picked up at 12:49:49/12:49 pm (local time epicenter) at a depth of 1.92 km (1 miles). Was there any damage? Did you feel it?

#Alta Sierra #CA #California City #Little Lake #Ridgecrest #United States

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joesbrownusa · 7 years

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Houses For Sale in Fort White, FL

SW Heflin Ave, Fort White, FL

Price: $35000

Santa Fe River Plantations 2.5 acre home site. Partially wooded with mature hardwoods in a desirable homes only neighborhood just minutes from High Springs. Trees are situated with a ready made home site. Easy access to the springs, rivers and parks on the Santa Fe, Suwannee and Itchetucknee rivers. You can choose your own builder and pick your own time frame to build. Very convenient to Lake City and Gainesville.

410 SW Buffalo Ct, Fort White, FL

Price: $110000

Spacious 4 Bedroom manufactured home located on just over 3 acres for sale. Just northeast of Ft. White and the Tustenuggee Road area, at the cul-de-cac of Buffalo Court lies a partially wooded home-site and a 2014 home that is move in ready. New carpet and a covered front porch have just been added to this 1976 square foot home. With 4 bedrooms, an open floor-plan and over three acres of land, this newly listed property is family friendly and convenient to Lake City, Gainesville and Fort White.

SW Riverside Ave, Fort White, FL

Price: $15500

WALKING DISTANCE TO THE ICHETUCKNEE & SANTE FE RIVERS! This vacant lot is across the street from the beautiful Ichetucknee river. A voluntary annual association fee of $100 gets you keys to all the parks and boat ramps on the Ichetucknee and Sante Fe Rivers in Columbia and Suwannee counties. You can float from any of these Three Rivers Parks, Hodor Park to Mid Point Park, Point Park or the Sante Fe River 3 Rivers Boat Ramp. Families that live in Three Rivers Estates refer to their properties as their own little piece of paradise. Come get your key to your own piece of paradise!

XX Sw Shellcracker Dr, Fort White, FL

Price: $22900

Luscious 3 acres of land located near the Santa Fe River with lots of potential!

SW Marynik Dr, Fort White, FL

Price: $49900

Beautiful 5 Acre Partially Wooded Lot on a Paved Road in River Rise Subdivision! Homes Only, Minimum 2000SF, Underground Utilities and Low Yearly HOA Fee! Close to O’Leno State Park, River Rise Preserve and the Santa Fe River! Only 5 mins to High Springs and Convenient to Gainesville and Lake City! Wonderful Country Setting to Build Your Dream Home! Low Columbia County Taxes Too!

Tbd Sw Tustenuggee Ave, Fort White, FL

Price: $28500

Country living on a paved road! Beautifully wooded acreage with frontage on Tustenuggee Ave. Perfect spot to build your new or manufactured home. Great location with easy drive into Lake City or convenient to I-75 access for Gainesville commuters. Just minutes from Oleno State Park and beautiful Ichetucknee Springs!

SW Longhorn Ter, Fort White, FL

Price: $13000

Walk to the River! Beautiful Heavily Wooded 1.25 acre lot in Cedar Springs Shores-Santa Fe River Community! Walk to the boatramp and have access to all the swimming, fishing, canoeing and snorkeling opportunities of pristine North Central Florida. Located just minutes from the town of Ft. White and just a skip to the unique towns of High Springs and Alachua with antique stores, specialty shops and fabulous restaurants. This is a rare find in a quiet river access neighborhood

1074 SW Santa Fe Dr, Fort White, FL

Price: $229000

Home on the beautiful clear Santa Fe River! Two bedroom home with wrap around porch overlooking the pristine waters of the Santa Fe River. Home has newer flooring and a remodeled bathroom. The open floor plan, porch, and expansive lower deck maximize the water front views. The dock at the waters edge complete this picturesque property. Voluntary $100/year HOA gives the owner access to the local parks and boat ramp.

535 SW Whisper Dr, Fort White, FL

Price: $249900

Immaculate 3/2 brick home features a huge master boasting spacious closets, dual sinks & tiled shower, open living area, formal dining room, wood-burning fireplace, huge kitchen with Island & breakfast room, 2 car garage, & more. Come enjoy the enclosed in-ground pool with large lanai, beautiful dogwoods, 20 X 22 shed with electric, pole barn, all situated on 5.01 beautiful acres. Priced to sell at $249,900. Located just minutes to the Springs.

Tbd Trenton Ter, Fort White, FL

Price: $8900

Nicley wooded .92 acre lot in Three Rivers Estates. An optional Home Owner’s Association Fee of approximately $100.00 per year will provide you with a key to all the private parks in the subdivision. Enjoy the river life of swimming, boating, fishing, tubing and day excursions with this HOA fee. North Florida living at it’s finest! Perfect for your site built or manufactured home! Priced at only $8,900.

1220 SW Bethlehem Ave, Fort White, FL

Price: $449900

Majestic One of a Kind 84 Acre Homestead! Rolling land with Gran-Daddy Oaks and a 10 Acre Pond as the Center Piece. Great Large Mouth Bass and Pan fishing! Property holds game and has nice grazing pastures. A section was left natural for the game. Includes Manufactured Home, Barn, Pavilion, Bungalow, Bath House w/extra laundry, Car Port. This is truly a must see! One of the most gorgeous properties listed in many years! Access is a paved road!

1805 SW Centerville Ave, Fort White, FL

Price: $119900

Move in ready large immaculate mobile on 4 beautiful acres, located just minutes to the head springs of the Itchetucknee State Park. Features large master bedroom with a seperate office within, fireplace in family room. Nice covered front and rear porches with seperate screened in cooking room . Workshop and seperate shed for mower. 6ft deep pool for those hot summer days. Koi pond . Short drive on graded road to pavement.

610 SW Cooper Ter, Fort White, FL

Price: $20000

This is a frame home that has been recovered with brick veneer. Home needs a lot of TLC. Also the path to the property is just that, buyer will need to inquire about an ingress or egress from property owners or check with property appraiser to see if one has ever been recorded. This is a cash transaction only. Sold “AS IS” No survey on file and the well, we think is on the property.

13118 SW State Road 47, Fort White, FL

Price: $129000

Beautiful well kept home with fantastic garage. Wonderful old oak grounds.

1634 SW Sunview St, Fort White, FL

Price: $154900

Very nice, lovingly cared for 4BR/2BA, with over 2200 SqFt on 5 acres featuring 2 wood burning stone fireplaces, crown molding, bullnose kitchen counters, tape & texture walls, sliding doors off the family room that open to a screened deck leading to the screened in-ground pool & wheel chair ramp. Other features include his & her closets, whirlpool tub, walk in shower, double vanity in master & double vanity in guest bath. This is a nice setup with the home set back from the road on a cul-de-sac & in a great location for easy access to Lake City, Ft. White, High Springs & Gainesville. T here’s even plenty of room for your small & large 4 legged friends as the property is completely fenced with lots of pasture.

1048 SW Kentucky St, Fort White, FL

Price: $27900

Handyman special 3/2 mobile home on .91 acres of beautifully wooded land. This spacious residence features a large family room, a split floor plan, vaulted ceilings & an open eat in kitchen with ample cabinet & counter space. The master retreat has a gracious private bath with garden tub & separate shower. Fantastic secluded property yet a short distance to Hwy 27, the Ichetucknee River, Springs & the Fort White town center. All Information recorded in the MLS is intended to be accurate but cannot be guaranteed, buyer advised to verify. Sold As-Is. No utilities will be turned on to this property and only cash/renovation loan offers with 0 day inspection period will be considered. Buyer should perform their due diligence/necessary inspections before submitting an offer.

13545 SW Tustenuggee Ave, Fort White, FL

Price: $88000

This Single-Family Home is located at 13545 Southwest Tustenuggee Avenue, Fort White, FL. 13545 SW Tustenuggee Ave is in the 32038 ZIP code in Fort White, FL. The average listing price for ZIP code 32038 is $134,780. 13545 SW Tustenuggee Ave has 3 beds, 2 baths, approximately 1,539 square feet, and was built in 1981

1435 SW Spirit Ave, Fort White, FL

Price: $59000

Bring your horses. This great home is down a country road off CR 138. Large kitchen, living room, and vaulted ceilings in family room. Every bedroom has a bathroom. Bar-b-que with friends on the big rear deck. On 2 acres. It is ready for horses with a 2 stall barn & tack room. There is also a large pole barn. It can be used as a carporte, workshop or you can keep it the way it is : a practice room for your band! Enjoy lower property taxes and the peace & quiet of country living. Neighborhood Description lots of animals. horses goats sheep chickens etc. near the Santa Fe river and 3 miles to Rum Island which is a popular spring and swimming hole. county park.

664 SW Kentucky St, Fort White, FL

Price: $76995

Country setting! This 3/2, 1,800 sq ft home has a spacious kitchen, built in cabinetry throughout home with plenty of storage. Move-in ready. Air conditioner will be installed by seller upon closing.

355 SW Magnolia Ln, Fort White, FL

Price: $220000

More photos coming soon! Superior built 3br/2ba home on 2 acres with soaring high ceilings and tile floors throughout the main living area. Nestled in Santa Fe River Plantations, this desired neighborhood is a deed restricted, homes only, horse friendly community. This well-kept home features an open split floor plan, extra large windows in the kitchen/breakfast area to allowing plenty of natural light, large bedrooms, a walk-in closet in the master, laundry room, stainless steel appliances in kitchen, breakfast bar, covered screened-in/covered patio and an extra large front and backyar d with scattered trees for ultimate privacy. There is a large 2 car garage and a new water softer. Just over the river and Columbia County line for lower taxes!! Enjoy the nearby springs, state parks, rivers, fishing and boating, equestrian trails, and unique shops. Just 25 minutes to Gainesville.

from Houses For Sale – The OC Home Search http://www.theochomesearch.com/houses-for-sale-in-fort-white-fl/ from OC Home Search https://theochomesearch.tumblr.com/post/158076773865

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