Oumota Week Day 1: Mythology AU & Established Relationship AU

I promise this is a ship thing!!! All those other guys are just set dressing! Anyway, I feel like the Vibe is strong enough even if they only have the vaguest most symbolic interaction here?

my favorite albums 2023

Morwan - Svitaye, Palaye Wayfarer - American Gothic Eusebeia - X Billy Woods & Kenny Segal - Maps Fluisteraars - De kronieken van het verdwenen kasteel - I & II Varg2™ - 10 år av skog, natt & stjärnor Protomartyr - Formal Growth In The Desert Debby Friday - Good Luck Geistaz'ika - Midnatsbøn ved djævelens port Raspberry Bulbs - The World Is Empty, The Heart Is Full

Ritual Howls - Virtue Falters Full Of Hell and Nothing - When No Birds Sang Fawn Limbs & Nadja - Vestigial Spectra 100 gecs - 10,000 gecs HEALTH - Rat Wars Hudson Mohawke x Nikki Nair - Set The Roof emptyset - ash Kode9 & Burial - Infirmary / Unknown Summer Turbid North - The decline Hexvessel - Polar Veil

Rahill - Flowers At Your Feet Driss El Maloumi - Aswat Fielded - Plus One Maxo - Even God Has A Sense Of Humor Acausal Intrusion - Panpsychism Lucifixion - Trisect Joys Of Pierced Hearts Body Void - Atrocity Machine Arnaut Pavle - Transylvanian Glare Lil Yachty - Let’s Start Here. Panopticon - The Rime of Memory

Black Wound - Warping Structure Shining - s/t JPEGMAFIA & Danny Brown - SCARING THE HOES EPROM - Syntheism Tirzah - trip9love…??? Miserere Luminis - Ordalie Brighde Chaimbeul - Carry Them with Us Anohni and The Johnsons - My Back Was A Bridge For You To Cross Agriculture - s/t Shapednoise - Absurd Matter

Akitsa - Devenir le diable Godflesh - Purge Swans - The beggar Boris and Uniform - Bright New Disease Sightless Pit - Lockstep Bloodwar Cattle Decapitation - Terrasite Kamaal Williams - Stings Urfaust - Untergang Melissa - II The Necks - Travel

Oxbow - Love's Holiday Tentacult - Lacerating Pattern Corrupted - Mushikeras Algiers - Shook Blackbraid - II Burial Hordes - Ruins Mary Lattimore - Goodbye, Hotel Arkada Anti-God Hand - Blight Year Martin Nonstatic - Pulsatille - Nocte Obducta - Karwoche - Die Sonne der Toten pulsiert

best of 2018

Best of 2020

Best of 2021

Best of 2022

gonna tag some people I would like to know what their favorites are: @aleprouswitch @musicktoplayinthedark @musicmakesyousmart @saisons-en-enfer @disease and whoever else would like to add please do

happy new year to the couple of active followers I have! much love!

This is a brief exploration of "Zanzo tests SPECTRA on himself". Maybe canon compliant, maybe not.

~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~~

"SPECTRA is designed to work on humans. Last I checked, I'm the only one with a brain in this room!" Zanzo drops into the office chair. He opens a panel on the underside of his bicep, exposing both a USB port and the rechargeable battery housed within. "Hook me up."

The PGR-101 on standby raises a hand. "Are you sure about this?"

Their boss rolls his eyes. "What kind of follower would I be if I weren't willing to sacrifice myself for the cause?"

The PGR-101 opens their mouth only to close it again. Pointing out that Zanzo tends to put his employees on the chopping block before himself is unnecessary at this moment. "Of course, sir." The plug clicks in the port, its attached wire snaking back towards the terminal.

"TODAY, please."

With the hit of the enter key, Zanzo's body slumps forward. Then he straightens up with a jolt, seeming alert apart from dull, unfocused eyes. "I am a proud member of the Vandelay family," he recites in monotone. "The labor I provide for this company is invaluable." Zanzo rises to his feet. With near mechanical motion, he widens his stance. One hand on rests on his hip and the other on the side of his head. He speaks again. "I don't see what you're upset about. This is how we progress. Human experimentation is a necessary step. I would think a scientist should understand..."

Click, program complete. Zanzo goes limp, collapsing into the chair. If PGR-101 had skin, it'd be crawling. "Boss?"

"It works," Zanzo says flatly. He repeats the phrase with a slow nod. Chilling compared to his usual excitement regarding projects. He yanks out the plug, shuddering as it clatters against the laminate floor. "Get out. I need to write an email." Zanzo dismisses the PGR-101 with a flourish of his wrist. Back to himself, like nothing happened.

Zanzo wheels over to the monitor, pulling up the email to draft a message for Kale Vandelay. So I finished testing SPECTRA and it works exactly as it should, Zanzo typed. Ready to move into the next phase whenever you are.

Press send. Wait. Zanzo shivers in his seat. This AI changes everything. The ability to seal away another's free will, their freedom of choice. It's out of his hands now.

Entrapdak Positivity Month - Ticket

Based on this Future AU with a fankid that was born from Twitter discussion between me and @entrapdaknation

So yeah TW for fankid I guess

***

In a quite corner of Crypto Castle lab, Entrapta was tending to Hordak’s cybernetic body.   What seemed like such an intimate moment had become routine over the years.

Even after all these years she still insisted on doing this maintenance by hand and refused to let Hordak use a machine.  As she tightened his loose connections, updated his operating software and cleaned out his ports, he sat topless and motionless except for scrolling his finger on his datapad.  He read out Queen Mermista’s woes on social media giggling all the while as the majority of these were self inflicted disasters. 

“There you go Sweety,” she announced while lubricating the last port, “that should keep you going for another while”

He smiled as he stretched his scrawny arms. Now that his chronic pain was eased, he had mobility again. “Thank you my Love,” he responded.

As she refitted his exoskeleton cables into his ports they were interrupted by a female clone who popped their her head out of a ventilation shaft. This clone bore more than a passing resemblance to both of them, “Momma, Papa, what’s this?”

This clone, Nebula Spectra Luminosity Neutrina (so special they gave her four names), had been quite the accidental addition to their family.  

Nebula had started life as a replacement body for Hordak.  A body where his defects had been genetically removed and replaced with Entrapta’s cells.  They never understood how this worked and gene splicing with other clone cells didn’t, but were glad something finally worked.  

Yet the body was still imperfect and somehow evolved past the initial plan of a hollow shell. They’d never been so pleased to have such a failure on their lab, and wept tears of joy after years of failure and frustration in conceiving naturally.  They finally had been blessed with a child of their own.  Unfortunately Nebula was forever stuck in an adult form like Hordak had been, a side effect of her initial conception as a cloned body.

Nebula popped her head out of a vent and held a small tattered piece of card in a hair tendril and was examining it closely.  She certainly had inherited Entrapta’s curiosity and somehow managed to find the most obscure items around the castle.

Entrapta plucked the card using her hair, used another tendril to flick down her second pair of glasses and read the words on the ticket. Instantly she lit up with the biggest smile.

“Oh Hordak do you remember?…” she started, “this is from…” she pointed at the faded words on the ticket with a hair tendril, as Hordak peered over and finished her sentence, “…our first date. Back when we viewed the roaming comet Rhullo”

“So where is it now?” questioned Nebula as she shuffled her tall frame out of the vent.

Hordak chuckled while Entrapta finished slotting in his exoskeleton parts

“Now that is the right question my Serendipitous Scion,” he smiled warmly at Nebula, “…for no one knows where it is n-”

“It blew up” interrupted Entrapta, who’d searched up the information on the datapad with a stray hair tendril.  

She looked dumbfounded at the Hordak, “did we blow that one up?”

Hordak thought for a moment, “…I don’t think so”

Nebula soaked up ever second of the exchange, “how many comets have you blown up?”

“Not man-“ started Entrapta. 

Hordak nudged her and winked, “-many that were inhabited”

Entrapta giggled and returned the wink in an overly theatrical way, “oh yeah..only the deserted ones.  Gotcha Honey”

“Momma, Pappa! When can I blow up a comet?”

Hordak ruffled the long hair on her crown, “when you’re old enough”

Nebula pouted, her hair fluffing up, “but I’m old enough nooooooow” she whined.

“Now Darling,” started Entrapta, “if our daughter is old enough to make her own fake ID, then she’s old enough to blow up a comet.”

Hordak sighed and folded his ears back as he stood up.

“Fine” he stated flatly

“Oh Pappa” Nebula exclaimed hugging her father tightly

“But on one condition…”

“Oh?”

He paused for a moment basking in her excitement

“Get your Big Siblings, they’ll want to see this too” he chuckled

For the Port Fest event, I can see Melody and Jillian being involved, what with their musical attributes and all. Melody has a concert at the end of the festival and Jillian joins the boys by adding her harp skills to their jazz band.

That's a really interesting idea!

It's something I will look into it once I will work on the Port Fest event, thank you for the idea! ^^

---------------------------------------------------------

TAG LIST :( a reblog will get you a place in the tag list! ^^)

@zebrabaker , @twistedwonderlxnd , @cowardlybravette , @iwilldietomorrowyees , @balsae , @shinypainterkid , @biscuitbirdpeach , @feuilleszuyu , @pale-lady-dreamer , @fanartreblogs , @kindestwalkingmentalbreakdown , @yue-caelum , @shuirosansshitposts , @sugarangel121 , @boddah-dreams , @icant-choosename-help , @lunartaravlar , @that-vixen , @houseoftitans , @epel-felmiers , @ur-secret-is-save-with-me , @myscalesofjustice , @palebyulsoo , @minnie-root , @smeraldo-flowers-for-you , @fandom-and-fanficlover-a-lot2005 , @yuu-did-what , @lovelyllamasblog , @justagirlwithtwokatanas , @roseberry-memories , @4mnd4aph , @xianeestrxnger , @la-chica-del-jardin-magico , @roseinbloom02 , @janellemeap , @not-someone-who-matters , @sach216 , @annastasha , @alexglitches , @peskygirl13 , @skag810 , @slumberingprincess-blog , @sam-spectra , @selfshipbabie , @quiet-oracle , @k0tln , @mysticsoulgirl , @autumnlover2018 , @bstormhands , @souleateralicestein , @fairyfel , @anime-discussions , @rgc2001 , @dracupie , @secretlawyercolorscissors , @idk-i-want-mcl-content , @tinkerblunder , @demigodseameg16 , @queenstardusts-blog , @lilmeowmeow7 , @qualityhistorygamingwinner , @boricua-suerte12 , @jasmineblogs43 , @plumass , @itz1the1meme234squad , @anonymousfanfictionlover-blog , @moonsungmylove , @food-lover9000 

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Tungsten hexacarbonyl CAS#: 14040-11-0

IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data Identification Product NameTungsten hexacarbonylIUPAC Namecarbon monoxide;tungstenMolecular StructureCAS Registry Number 14040-11-0EINECS Number237-880-2MDL NumberMFCD00011462Beilstein Registry NumberNo data availableSynonymstungsten hexacarbonyl, hexa-carbonyltungstate(0), hexacarbonyl tungsten(0), tungsten(0) hexacarbonyl, hexacarbonyltungsten(0), hexacarbonyltungsten(O), hexacarbonyl tungsten;CAS Number: 14040-11-0;CAS No.: 14040-11-0Molecular FormulaC6O6WMolecular Weight351.9InChIInChI=1S/6CO.W/c6*1-2;InChI KeyFQNHWXHRAUXLFU-UHFFFAOYSA-NCanonical SMILES#.#.#.#.#.#. Patent InformationPatent IDTitlePublication DateUS2016/24119ELECTRONIC DEVICE COMPRISING METAL COMPLEXES2016EP2733148Tungsten complexes with di-dentate ligands2014 Physical Data AppearanceWhite crystalline powderSolubilityinsolubleFlash Point200°CSensitivity4: no reaction with water under neutral conditions Density, g·cm-3Measurement Temperature, °CType (Density)2.6519.84crystallographic Description (Association (MCS))Association with compound Spectra Description (NMR Spectroscopy)Nucleus (NMR Spectroscopy)Solvents (NMR Spectroscopy)Temperature (NMR Spectroscopy), °C Spectrum13Cbenzene-d6Chemical shifts13Cbenzene-d621.8413Cchloroform-d12513Cnot givenSpectrum13C(2)H8-toluene-30Linewidth of NMR absorption13CCDCl330Linewidth of NMR absorption17OCDCl321Spectrum183Wsolid Description (IR Spectroscopy)Solvent (IR Spectroscopy)Temperature (IR Spectroscopy), °CSignals, cm-1ATR (attenuated total reflectance), BandsBandshexaneIntensity of IR bands, Bandspotassium bromideBandshexane1983BandsKBr1977Bandspotassium bromide1982Bandsgas1.84 - 151.84Bandspolyethylene-83.161980.3 Description (Mass Spectrometry)Comment (Mass Spectrometry)electron impact (EI), spectrumSpectrumFragmentation patternSpectrumMolecular peak, Fragmentation patternFragmentation patternMolecular peakMolecular peak, Fragmentation pattern Description (UV/VIS Spectroscopy)Solvent (UV/VIS Spectroscopy)Comment (UV/VIS Spectroscopy)Absorption Maxima (UV/VIS), nmSpectrumhexane195 nm - 500 nmSpectrumtetrahydrofuran300 nm - 450 nmSpectrum, Band assignmenthexane375 nm - 720 nmBand assignmentmethylene chloride=methylene dichloride226 nm - 286 nmSpectrum, Band assignmentcyclohexane100 nm - 355 nmBand assignmentmethylene chloride=methylene dichloride288.6Spectrum, Band assignmentmethyl cyclohexane300 nm - 600 nmSpectrum, Band assignmentacetonitrile212.766 nm - 322.581 nm Description (Raman Spectroscopy)BandsRaman Tungsten hexacarbonyl CAS#: 14040-11-0 IRTungsten hexacarbonyl CAS#: 14040-11-0 XRD Route of Synthesis (ROS) Route of Synthesis (ROS) of Tungsten hexacarbonyl CAS 14040-11-0 ConditionsYieldWith trimethylamine-N-oxide In methanol; benzene byproducts: CO; addn. of soln. of TMNO in methanol to soln. of W(CO)6 in benzene, stirring, then addn. of bipy, stirring, 18h, 28°C, evapn., filtration; recrystn. from CH2Cl2/hexane; elem. anal.;97%In hexane Irradiation (UV/VIS); under N2, excess 2,2'-bipyridine, photolysis with a 200 W Hg lamp; pptn. washed with n-hexane, column chromy. on alumina, recrystn. (CH2Cl2/hexane);80%With sodium tetrahydroborate In butan-1-ol at 105℃; under 760.051 Torr; for 0.333333h; Microwave irradiation; Inert atmosphere; Green chemistry;Experimental ProcedureGeneral Preparation of Mo(CO)4dppe, 2cGeneral procedure: The reactions were run in a CEM Corp. MARS microwave fitted with a fiber optic temperature probe and a port on top for a reflux condenser.1 mmol of Mo(CO)6 and dppe (0.425 g, 1.1 mmol) were combined with 20 mL of 1-propanol in a two-neck 100 mL RB flask. To this mixture was added NaBH4 (0.128 g, 3.3 mmol). The flaskwas placed in themicrowave and a reflux condenser attached through a hole in the top of the microwave. The mixture was sparged with nitrogen. The mixture was heated under nitrogen at 400 W for 1.5 min to reach reflux temperature. Once the reflux temperature was reached the microwave power was reduced and the temperature maintained for 18 min. The mixture was cooled to room temperature and 2-4 mL of water was added to the reaction to dissolve excess NaBH4 and promote product precipitation. The reaction was cooled -10 °C for several hours. The light yellow complex was filtered in air and washed with 2×5 mL of petroleum ether/diethyl ether(1:1) mixture resulting in 580 mg of Mo(CO)4dppe after drying, a 95% yield.80% Safety and Hazards GHS Hazard StatementsNot ClassifiedSDS DownloadEnglish Version Other Data TransportationClass 6.1; Packaging Group: III; UN Number: 3466Under the room temperature and away from lightHS Code293190StorageUnder the room temperature and away from lightShelf Life1 yearMarket PriceUSD DruglikenessLipinski rules componentMolecular Weight351.912HBA6HBD0Matching Lipinski Rules3Veber rules componentPolar Surface Area (PSA)0Rotatable Bond (RotB)0Matching Veber Rules2 Use PatternChemical processes/laboratory usecatalyst in method of making a 2-(2,3-epoxypropyl)phenolContrast agent in diagnostic imagingContrast agent in X-ray imaging of atherosclerotic plaqueContrast agent in X-ray imaging of liver tumorsX-ray contrast agentContrast agent in vivo imaging of kupffer cells Purity CalculationTungsten hexacarbonyl partially dissolves in mixed acids and cannot be directly determined by ICP for the tungsten content in the product. Therefore, impurities in tungsten hexacarbonyl are first dissolved out by mixed acids, and the impurity content in the pure tungsten hexacarbonyl is tested by ICP. The purity of tungsten hexacarbonyl is obtained using the impurity reduction method.The theoretical content of tungsten in tungsten hexacarbonyl is52.23% Read the full article

*Toccata and Fugue in D Minor intensifies*

I'M BACK FROM THE DEAD, BABY!

Actually I never left, I just haven't been keeping the place running in all this time.

*blows dust off of record player*

Does this thing still work? Time to find out! Harvest Chill coming back to drop the sweet tunes for all the fillies, colts, & non-binary folks! (I kinda made myself cringe there a little)

Gotta shake off the dust & rust with one of my all-time faves!

Seagull - Fritzybeat & Port Blue (Spectra Remix)

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Oumota Weekend Day 3: Pre-game & Post-game & Free Prompt

You could also interpret this as post-game, I think? I had a really strong image in mind from the start for this one. Just thinking about character roles again

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TOTAL STATION NIKON DTM-322 5'

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Total Station Nikon DTM 322 (Single)

Nikon DTM 322. Total station Nikon DTM-322 is an economic, versatile, prism-based 5” total station. Nikon’s legendary optics effectively allow in more light to give brighter, clearer images even in low-visibility conditions typical in the field. Total station Nikon DTM 322 is among the fastest total stations in its class.

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Rough Patch

Early CoV

Tyreen paced up and down the length of the Cathedral infirmary waiting room. She was glad that aside from the glass door, the walls of the room were thick metal. The God-Queen couldn’t be caught nervously wringing her hands as she paced like a captive lion. Not that she looked like the God-Queen when she was draped in a too big hooded jacket over a thin tank top, however she couldn’t settle down or stop herself. Troy was in surgery; perhaps the most extensive operation he’d been through besides breaking his jaw when they were teenagers.

She took a deep breath and reminded herself that it would be ok, that this was necessary. It wasn’t his fault he was so fragile, a fact that had been repeated to her by her parents since they’d been born back on Nekrotafeyo. She’d always had to be strong while she watched their parents dote over him, their mother boosting him with her own siren energy when he was running low. Tyreen had never been sickly, only catching a cold once or twice in her childhood,and she had never been severely injured before the incident with the guardians.It had always been so hard to wrap her head around the fact that her twin brother, who had once even been a part of her could be so sickly in return.

It was for that reason that Tyreen was grateful when Allison had sat her down and explained in great detail what they would be doing to Troy in this operation. She had been the one to catch that the scrap contraption Troy called a right arm was pulling his spine out of alignment and exacerbating a congenital defect in his vertebra. Without this operation the damage would worsen,and the neurological symptoms would become unavoidable. Allison had also gotten Troy to agree to getting a neural port installed so that he could actually use the arm instead of just hanging off him like the hunk of scrap it was.

None of that helped now,though,she was still anxious about what was going on beyond the waiting room door. In her mind, images flashed of her brother flayed open on a cold operation table picked through like an animal being dissected. Their fathers' warnings of what the corporations would do to them repeated over these images. She hated how the infirmary smelled, so sterile and clean. It felt fake like that, especially here on Pandora. Nothing should be this clean not even if it was a medical practice.

Tyreen stopped her pacing and shook her head, this was ridiculous. Allison Spectra was the woman who had saved them when she had been sure Troy was about to die in the Promethean slums. She had been their doctor for years at this point there was no reason to think she would suddenly be untrustworthy, especially when she’d brought in one of the best neurosurgeons in the six galaxies to aid in the operation. Troy was literally in the most capable hands he could be in, she just needed to relax.

She sat down in the chair she had left her bag on and fished out her echo-phone. Everyone in the Inner Circle knew what was going on, and Juni had assured her that they would handle things until Troy was stable. Tyreen still couldn’t help but check in on the morning reports, Jaxon had just finished leading the sermon. While it was a relief that the Children of the Vault could run itself without her constant supervision. Tyreen felt like it was all she had control of in this moment. If she truly needed to, she could phone Juni and have her do whatever she needed done, of course she knew that she should just let it rest, for now, and focus on the things at hand but it was comforting to know that one thing at least was always in her control.

She did however open the channel she used to talk to all the department heads. The moment her icon took a green aura indicating she was online she immediately got pinged by Juni.

Juniper (Marketing) : TYREEN! Turn it off!

Juniper (Marketing): You promised you’d look after yourself, micromanaging us isn’t looking after yourself Tyreen. I can handle things while you worry about yourself and Troy, Jaxon is on the alert too she promised to handle anything that comes her way.

Tyreen huffed at the messages, even though they made her feel fuzzy inside. Knowing that Juni was looking after her she couldn’t just not answer.

Tyreen (God Queen): Thanks. I’ll head off now, you remind me to get you a gift basket or three when this is handled.

She closed the app and sifted through some current news articles looking for anything to distract her. Until the door clicked open, one of the nurses stepped out and was almost immediately accosted by Tyreen.

“Is it done? Is he ok? He’s ok right?”Tyreen would never act like this if she thought it would get out into the general public but the medical team was sworn to secrecy the same way the department heads were.

“God-Queen, we aren’t done quite yet. Dr.Spectra wanted to speak with you. She’ll be out in a moment.”The nurse said in a tone that had anyone else used they would have found themselves husked. Today though nobody would be husked, these people were here to do a job.

The nurse disappeared back behind the door and after what felt like entirely too long the familiar face of Allison Spectra stepped into the room. Most of her definable features were masked off by her surgical scrubs but her amber eyes that softened when they focused on Tyreen were unmistakable.

“Ah Tyreen, don’t worry everything’s been going perfectly fine. We’ve installed all the vertebral implants and Dr.Sampson is getting ready to install the neural port. Actually that’s what I wanted to speak with you about, as I’m sure you can imagine it’s a bit of a delicate process and while Dr.Sampson is the best neuro specialist in this arm of the galaxy things can still be a little tricky.”Allison held up a hand as Tyreen began to glare at her.

Tyreen weighed the words carefully. She did not want to jump to any conclusions but Allison more so than anybody else in the CoV would know how seriously Tyreen took her brother's health. How could she not when she had been the one who had found a freshly rained on frantic eighteen year old in the lobby of her private practice on Promethea sobbing and begging for help, that her brother was sicker than he’d ever been. Allison had only ever been here to help, and she knew that.

“Shouldn’t you, y’know be in there then? Not out here with me?”She said after what felt like an insufferably long pause. Surely if the operation was not done, one of the attending physicians shouldn’t be out here with her just because she was wearing a track into the floor.

“I’m not a neurosurgeon if you’ll recall,the nurses can handle watching his vitals. There’s no reason for me to be clogging up the operating room when there’s nothing more I can do.”Allison took her mask and gloves off, shoving them into a pocket of her operating scrubs, then placed a gentle hand on Tyreens leg.”Besides, I figured you could use some company.”

Tyreen said nothing to that. It was true she could use the company. How often did she forget that despite all her bluster she was a person, there was only so much she could shoulder by herself before the bottled up emotions ran over. She said nothing but let the hand remain, a good little reminder that she deserved the comfort of others.

——

Tyreen didn’t know what to expect when she walked into Troy’s hospital room. The only force driving her forward right now was the need for visual confirmation that her twin was alive and well. Dr.Sampson had used a lot of big medical terms she didn’t really understand while telling her the operation had been successful. To be honest her brain had mostly blocked out everything he’d said after confirming that Troy had taken all the implants well. She knew that anything that she needed clarification on she could turn to Allison for, but nothing would settle her other than seeing Troy herself.

Nothing could have prepared her for what she saw when she entered the room. Time seemed to slow around her as she looked at the heavily bandaged figure that lay in the hospital bed. Her mind immediately registered him as her brother. However,he looked so different in that moment, even when he’d needed his jaw glued back together he still looked like Troy. Laying in the bed now he looked so small.

She was transported back in an instant to Nekrotafeyo, to the days when she would be pulled by her father kicking and screaming away from the bed while her mother would cradle Troy’s tiny body in her lap, how still he would be sometimes. This was just like that only mom and dad weren’t here now to stroke her hair and tell her everything would be alright.

Allison and Dr.Sampson had both warned her that it wouldn’t be pretty, that there would probably be blood seepage,but not to worry unless it seemed excessive.Even so,the bloodstained bandages caught her attention.She was glad that Troy was being pumped full of the best pain killers on the market because even without seeing what lay under the bandages it looked so painful.

It took every ounce of self-control she had to not just touch him with her powers and take the pain away. The doctors had been very clear with her that she could not make the same mistake she’d made with his jaw. He would be laid up for a month at the longest;they had to let his body heal naturally or he would likely be paralyzed if not worse. She perched in the chair by his bedside so afraid that if she were to so much as breathe on him he would turn to dust before her eyes.

She hummed softly, the old lullaby their mother used to sing when they were scared or afraid. Leda had so many lullabies that Tyreen felt like she did no justice to. They were, however, one of the last tenuous strands to their mother they had left and in this moment she needed the strength that Leda had always had.

***

Tyreen was determined to sit vigil at her brother's bedside; she hadn��t left the room in days. When the medical team would come in to check on him she’d excuse herself to the bathroom or go stand in the hallway. She had seen them change his bandages once and that had been one time too many for her. Allison asked her if she’d eaten every time she came in and Tyreen lied through her teeth, she hadn’t left the infirmary ward at all, for once in her life her ability to sustain herself without eating was useful.

She’d fallen out of the habit of checking her echo every ten minutes, if someone needed her attention so desperately they could message her. She was deep in thought when movement at the door caught her attention and Juniper walked in. Tyreen had forgotten that she’d given Juni permission to enter the ward if she so chose to, but she was glad to see a familiar face from outside the ward.

“Hey.”

“Hey.” Tyreen echoed back at her, her gaze never straying. Juniper dragged a chair from the corner of the room and sat next to her God-Queen.

“How’s he doing?” She asked, placing a hand on Tyreen’s shoulder.

“Fine. They’re gonna have him sleep through the worst of it.”

“And how are you doing chica? You look like you haven’t slept in days.”

“I haven’t. Not really at least. I’ve caught a few hours here and there but…I just worry something awful will happen to him while I sleep.” Tyreen rubbed her eyes, she felt like a ghost of herself.

“You can’t hold yourself responsible for that Tyreen. You know that right? This is out of your hands now.” Juni soothed giving the other woman's leg a reassuring squeeze.

“I can though. This is my fault, the fact that he needed the operation at all, the fact he’s so sick all the time. All of it.”

“Would you blame yourself if he was like this and you hadn’t been born the way the both of you had been?”

Silence met the question and after a long pause with no answer in sight Juniper sighed.“ I get it. He’s your family, he’s all you got, but that doesn’t mean you can tear yourself apart like this.”

She sighed again and looked to the door before looking back at Tyreen. “Listen, when I was just a little younger than you my family lived in the Promethean slums. Folks didn’t care about what ended up in the air or water cos we were the underbelly and they were progress. I had a younger sister and I had to sit and watch as she got sicker and sicker and nobody gave a damn. I had to watch my sister suffer and die and accept there wasn’t a damn thing I could do about it. As the older or stronger sibling we so often feel like it’s on us alone to protect our siblings, but we can’t do it all Tyreen.”

“Troy’s a tough guy, and you're literally sitting in one of the best medical facilities on Pandora. He’ll be alright and if he does need you? Shouldn’t you be in the best condition you can be to provide for him. Please just get something to eat, have a nap. I’ll stay here and watch him for you Ty.”

Tyreen looked up at Juniper, there were tears in both of their eyes and a look of understanding Tyreen had never seen from another person before. She had always thought her burdens were things she couldn’t share with anyone else, she hadn’t even considered that other people would feel powerless in such a situation. She figured that regular people just accepted that other peoples lives were out of their control. For Juniper to understand her pain and be willing to watch over Troy in her place, it touched her. Juniper was among the few people Tyreen considered a genuine friend and this only cemented that thought for her.

She got up slowly, feeling a bit dizzy. Perhaps she did need to eat more than she thought she did. She gave Juniper a small tired smile.

“Promise you’ll call if anything changes.”

“You’ll be the first to know hun.” Juni patted her shoulder and tilted her head towards the door. “Go on, go take care of yourself.”

Oh...

So, I’ve just had a certain conversation in Byzantium, during The Outer Worlds. And I know now what’s actually going on in Halcyon.

Oh, crap.

Also, MASSIVE spoilers. Do not read this unless you’ve at least got to Byzantium and talked to a certain rogue academic. (If you’re scratching your head about what I’m referring to here, AVOID this post. Seriously.)

They’re running out of food.

Fuck.

Or actually, if I’m parsing the context correctly, there are enough crops, but the nutritional balance is all wrong. People just aren’t getting the right vitamins and minerals. Bluntly, the Halcyon Colony is utterly shafted.

Thinking about it, several things immediately make sense.

1. The abandonment of the Hope. The Board think they’re keeping down the number of hungry mouths this way.

2. The sheer volume of hyper-aggressive marauders. This was something that had been nagging me. Given how bad conditions are in the corporate towns, I had wondered why more people didn’t just turn deserter, quietly walk away and found their own townships out in the great empty. In fact it’s likely that lots of people have tried, only to find their vegetable gardens fail to bloom, either forcing them back to the townships, or into violent aggression. (The marauders behave the way they do because they’re basically starving.)

Abigale’s group were able to survive because they were lucky enough to have the resources of a full botanical laboratory, which presumably gave them an edge no-one else had.

3. The passivity of the near-enslaved corporate populations. Vitamin deficiencies and protein deficiency can impair cognitive function. Potassium springs to mind, here. (Your nervous system works partly through the exchange of potassium ions; without them, the electrics literally stop.) People are exhausted, tired, ill ... and just can’t think straight anymore.

One wonders if perhaps the star Halcyon has slightly-odd, non-solar chemical element abundance-ratios, and there’s less potassium than in Sol? This would in turn affect the chemistry of Halcyon’s planet-forming disc, which would in turn alter the chemistry of planetary soils, so...

(Also, what a fucking stupid mistake on the Board’s part. Did they not think to take a fucking spectrum of the star’s light? A simple back-to-back comparison with Sol would tell you something was off! For fuck’s sake, there’s a massive potassium feature at 1.27 microns! It’s prominent enough that you can resolve the fucker in brown dwarf spectra, for goodness sake! It’s not subtle! AAAAAAaaaaargh! Did they even talk to a single scientist when they started this colony?)

4. The Board’s weird fixation on expansion onto Groundbreaker. On the face of it, it’s not really that obvious why they’re so obsessed with it. I mean, Groundbreaker is a useful port, yes, but they could build their own, right?

But Groundbreaker is also an actual fucking starship.

The Board is trying to muscle in onto Groundbreaker because in the worst-case scenario, Groundbreaker could fucking leave.

5. The weird fixation on saltuna on Terra 2, despite the fact that the fish won’t thrive there. On the face of it, this is mad. Wandering around Edgewater, I was puzzled by the absence of vegetable gardens. Why didn’t they just try growing normal food instead, out on all the fields outside? I assumed it was due to the security situation, related to all the marauders. Actually what I suspect is going on now is that the Board is just fucking desperate, and clutching at straws.

6. And the kicker? Here’s why the Board fundamentally CAN’T solve Halcyon’s problems...

The other thing is that there’s a very obvious solution the Board has apparently bypassed: vitamin pills.

But of course to make it work, you’d have to give them to everyone in the colony - it’s a collective-action problem, not an “unsympathetic individuals with bad life choices” thing. Basically, it’s the sort of thing - in economics jargon, an “externality” - that you have to pay for through general taxation. The Board has zero popular legitimacy - it’s a self-selecting oligarchy - and governs through an extremist-libertarian ideology. It can’t adopt any kind of collective-action response, because every aspect of its own ideological structure militates against it.

It’s actually possible that the Board haven’t even thought about issuing vitamin pills.

Also, it explains why Dr Chartrand is dealing with such poor resourcing. Frankly, in context, it’s no surprise her project is in a mess. In fact, it’s actually a minor miracle that it exists at all.

7. Why has it taken 70 years for the situation to reach near-meltdown?

At a guess, I think because of shipping coming in through Groundbreaker. Perhaps until relatively recently, the Board was able to import enough goods to somewhat-offset the growing food crisis throughout Halcyon. However, as ambient conversations on Groundbreaker make clear, the galactic economy is apparently now in recession, and interstellar trade is drying up. Food imports will consist of lots of large, high-mass items that take up a lot of space and have high shipping costs, so across interstellar distances, profits will be marginal even in the good years. In the bad years, my guess would be that the remaining interstellar shipping firms will retrench to things like luxury goods - small items that carry high prices, so have higher margins. Which in turn means that they’ll be carrying fewer and fewer shipments of basic goods.

Again, it’s capitalism that’s killing Halcyon.

8. This also explains Catherine’s obsession with controlling a boarst factory.

I thought she was just a bit mad. Actually she’s not. She’s either trying to corner the market in one of the few remaining foodstuffs, or she’s just looking out for herself - but either way, it does make some sense.

9. Mass Effect had Virmire, The Outer Worlds has Byzantium.

This is very much that kind of “oh my fucking goodness” moment.

Don’t mind me, I’m going to be a while digesting the implications of all of this.

Tungsten hexacarbonyl CAS#: 14040-11-0

IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data Identification Product NameTungsten hexacarbonylIUPAC Namecarbon monoxide;tungstenMolecular StructureCAS Registry Number 14040-11-0EINECS Number237-880-2MDL NumberMFCD00011462Beilstein Registry NumberNo data availableSynonymstungsten hexacarbonyl, hexa-carbonyltungstate(0), hexacarbonyl tungsten(0), tungsten(0) hexacarbonyl, hexacarbonyltungsten(0), hexacarbonyltungsten(O), hexacarbonyl tungsten;CAS Number: 14040-11-0;CAS No.: 14040-11-0Molecular FormulaC6O6WMolecular Weight351.9InChIInChI=1S/6CO.W/c6*1-2;InChI KeyFQNHWXHRAUXLFU-UHFFFAOYSA-NCanonical SMILES#.#.#.#.#.#. Patent InformationPatent IDTitlePublication DateUS2016/24119ELECTRONIC DEVICE COMPRISING METAL COMPLEXES2016EP2733148Tungsten complexes with di-dentate ligands2014 Physical Data AppearanceWhite crystalline powderSolubilityinsolubleFlash Point200°CSensitivity4: no reaction with water under neutral conditions Density, g·cm-3Measurement Temperature, °CType (Density)2.6519.84crystallographic Description (Association (MCS))Association with compound Spectra Description (NMR Spectroscopy)Nucleus (NMR Spectroscopy)Solvents (NMR Spectroscopy)Temperature (NMR Spectroscopy), °C Spectrum13Cbenzene-d6Chemical shifts13Cbenzene-d621.8413Cchloroform-d12513Cnot givenSpectrum13C(2)H8-toluene-30Linewidth of NMR absorption13CCDCl330Linewidth of NMR absorption17OCDCl321Spectrum183Wsolid Description (IR Spectroscopy)Solvent (IR Spectroscopy)Temperature (IR Spectroscopy), °CSignals, cm-1ATR (attenuated total reflectance), BandsBandshexaneIntensity of IR bands, Bandspotassium bromideBandshexane1983BandsKBr1977Bandspotassium bromide1982Bandsgas1.84 - 151.84Bandspolyethylene-83.161980.3 Description (Mass Spectrometry)Comment (Mass Spectrometry)electron impact (EI), spectrumSpectrumFragmentation patternSpectrumMolecular peak, Fragmentation patternFragmentation patternMolecular peakMolecular peak, Fragmentation pattern Description (UV/VIS Spectroscopy)Solvent (UV/VIS Spectroscopy)Comment (UV/VIS Spectroscopy)Absorption Maxima (UV/VIS), nmSpectrumhexane195 nm - 500 nmSpectrumtetrahydrofuran300 nm - 450 nmSpectrum, Band assignmenthexane375 nm - 720 nmBand assignmentmethylene chloride=methylene dichloride226 nm - 286 nmSpectrum, Band assignmentcyclohexane100 nm - 355 nmBand assignmentmethylene chloride=methylene dichloride288.6Spectrum, Band assignmentmethyl cyclohexane300 nm - 600 nmSpectrum, Band assignmentacetonitrile212.766 nm - 322.581 nm Description (Raman Spectroscopy)BandsRaman Tungsten hexacarbonyl CAS#: 14040-11-0 IRTungsten hexacarbonyl CAS#: 14040-11-0 XRD Route of Synthesis (ROS) Route of Synthesis (ROS) of Tungsten hexacarbonyl CAS 14040-11-0 ConditionsYieldWith trimethylamine-N-oxide In methanol; benzene byproducts: CO; addn. of soln. of TMNO in methanol to soln. of W(CO)6 in benzene, stirring, then addn. of bipy, stirring, 18h, 28°C, evapn., filtration; recrystn. from CH2Cl2/hexane; elem. anal.;97%In hexane Irradiation (UV/VIS); under N2, excess 2,2'-bipyridine, photolysis with a 200 W Hg lamp; pptn. washed with n-hexane, column chromy. on alumina, recrystn. (CH2Cl2/hexane);80%With sodium tetrahydroborate In butan-1-ol at 105℃; under 760.051 Torr; for 0.333333h; Microwave irradiation; Inert atmosphere; Green chemistry;Experimental ProcedureGeneral Preparation of Mo(CO)4dppe, 2cGeneral procedure: The reactions were run in a CEM Corp. MARS microwave fitted with a fiber optic temperature probe and a port on top for a reflux condenser.1 mmol of Mo(CO)6 and dppe (0.425 g, 1.1 mmol) were combined with 20 mL of 1-propanol in a two-neck 100 mL RB flask. To this mixture was added NaBH4 (0.128 g, 3.3 mmol). The flaskwas placed in themicrowave and a reflux condenser attached through a hole in the top of the microwave. The mixture was sparged with nitrogen. The mixture was heated under nitrogen at 400 W for 1.5 min to reach reflux temperature. Once the reflux temperature was reached the microwave power was reduced and the temperature maintained for 18 min. The mixture was cooled to room temperature and 2-4 mL of water was added to the reaction to dissolve excess NaBH4 and promote product precipitation. The reaction was cooled -10 °C for several hours. The light yellow complex was filtered in air and washed with 2×5 mL of petroleum ether/diethyl ether(1:1) mixture resulting in 580 mg of Mo(CO)4dppe after drying, a 95% yield.80% Safety and Hazards GHS Hazard StatementsNot ClassifiedSDS DownloadEnglish Version Other Data TransportationClass 6.1; Packaging Group: III; UN Number: 3466Under the room temperature and away from lightHS Code293100StorageUnder the room temperature and away from lightShelf Life1 yearMarket PriceUSD DruglikenessLipinski rules componentMolecular Weight351.912HBA6HBD0Matching Lipinski Rules3Veber rules componentPolar Surface Area (PSA)0Rotatable Bond (RotB)0Matching Veber Rules2 Use PatternChemical processes/laboratory usecatalyst in method of making a 2-(2,3-epoxypropyl)phenolContrast agent in diagnostic imagingContrast agent in X-ray imaging of atherosclerotic plaqueContrast agent in X-ray imaging of liver tumorsX-ray contrast agentContrast agent in vivo imaging of kupffer cells Purity CalculationTungsten hexacarbonyl partially dissolves in mixed acids and cannot be directly determined by ICP for the tungsten content in the product. Therefore, impurities in tungsten hexacarbonyl are first dissolved out by mixed acids, and the impurity content in the pure tungsten hexacarbonyl is tested by ICP. The purity of tungsten hexacarbonyl is obtained using the impurity reduction method.The theoretical content of tungsten in tungsten hexacarbonyl is52.23% Read the full article